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Electrochemical study of corrosion inhibition and adsorption behaviour for pure iron by polyacrylamide in H2SO4: Synergistic effect of iodide ions
Umoren, S. A.1,2; Li, Y.1; Wang, F. H.1
通讯作者Li, Y.(yiling@imr.ac.cn)
2010-05-01
发表期刊CORROSION SCIENCE
ISSN0010-938X
卷号52期号:5页码:1777-1786
摘要Corrosion inhibition and adsorption behaviour for pure iron in 0.5 M H2SO4 by polyacrylamide (PA) were investigated using electrochemical techniques. The effect of iodide ion additives was also studied. It was found that inhibition efficiency increased with PA concentration. Corrosion inhibition was afforded by adsorption of PA onto the metal following El-Awady kinetic thermodynamic adsorption isotherm model via chemisorption mechanism. A mixed inhibition mechanism is proposed for the inhibitive effects of PA as revealed by potentiodynamic polarization technique. A synergistic effect was observed between PA and KI as evident from the values of synergism parameter found to be greater than unity. (C) 2010 Elsevier Ltd. All rights reserved.
关键词Iron Polyacrylamide Iodide ion Adsorption Corrosion inhibition Synergism
资助者Chinese Academy of Sciences (CAS) ; Academy of Sciences for the Developing World (TWAS)
DOI10.1016/j.corsci.2010.01.026
收录类别SCI
语种英语
资助项目Chinese Academy of Sciences (CAS) ; Academy of Sciences for the Developing World (TWAS)
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号WOS:000277224400029
出版者PERGAMON-ELSEVIER SCIENCE LTD
引用统计
被引频次:162[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/100308
专题中国科学院金属研究所
通讯作者Li, Y.
作者单位1.Chinese Acad Sci, Inst Met Res, State Key Lab Corros & Protect, Shenyang 110016, Peoples R China
2.Univ Uyo, Fac Sci, Dept Chem, Uyo, Nigeria
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Umoren, S. A.,Li, Y.,Wang, F. H.. Electrochemical study of corrosion inhibition and adsorption behaviour for pure iron by polyacrylamide in H2SO4: Synergistic effect of iodide ions[J]. CORROSION SCIENCE,2010,52(5):1777-1786.
APA Umoren, S. A.,Li, Y.,&Wang, F. H..(2010).Electrochemical study of corrosion inhibition and adsorption behaviour for pure iron by polyacrylamide in H2SO4: Synergistic effect of iodide ions.CORROSION SCIENCE,52(5),1777-1786.
MLA Umoren, S. A.,et al."Electrochemical study of corrosion inhibition and adsorption behaviour for pure iron by polyacrylamide in H2SO4: Synergistic effect of iodide ions".CORROSION SCIENCE 52.5(2010):1777-1786.
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