| A Study of Spin-Hamiltonian Parameters and Defect Structure for Co2+ Ion in the Tetragonal Zn2+ Site of Ba2ZnF6 Crystal | |
| Li, Bang-Xing1; Zheng, Wen-Chen1,3; Yang, Wei-Qing1,2 | |
| Corresponding Author | Zheng, Wen-Chen(zhengwc1@163.com) |
| 2010-10-01 | |
| Source Publication | ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
 |
| ISSN | 0932-0784 |
| Volume | 65Issue:10Pages:877-881 |
| Abstract | The spin-Hamiltonian (SH) parameters (g factors g(parallel to), g(perpendicular to) and hyperfine structure constants A(parallel to), A(perpendicular to)) for the Co2+ ion in the tetragonal Zn2+ site of a Ba2ZnF6 crystal are calculated from the second-order perturbation formulas based on the cluster approach for the SH parameters of 3d(7) ions in tetragonal symmetry with the effective spin S = 1/2. In the calculations, a reduction factor due to the dynamical Jahn-Teller effect is used. The calculated results are in reasonable agreement with the experimental values, suggesting that the dynamical Jahn-Teller effect should be considered here. The defect structure of the Co2+ center in Ba2ZnF6:Co2+ is also obtained from the calculations. The results are discussed. |
| Keyword | Electron Paramagnetic Resonance (EPR) Crystal- and Ligand-Field Theory Defect Structure Co2+ Ba2ZnF6 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Research Area | Chemistry ; Physics |
| WOS Subject | Chemistry, Physical ; Physics, Multidisciplinary |
| WOS ID | WOS:000286153200017 |
| Publisher | VERLAG Z NATURFORSCH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/100460 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Zheng, Wen-Chen |
| Affiliation | 1.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China 2.Chengdu Univ Informat Technol, Dept Opt & Elect, Chengdu 610225, Peoples R China 3.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Li, Bang-Xing,Zheng, Wen-Chen,Yang, Wei-Qing. A Study of Spin-Hamiltonian Parameters and Defect Structure for Co2+ Ion in the Tetragonal Zn2+ Site of Ba2ZnF6 Crystal[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,2010,65(10):877-881. |
| APA | Li, Bang-Xing,Zheng, Wen-Chen,&Yang, Wei-Qing.(2010).A Study of Spin-Hamiltonian Parameters and Defect Structure for Co2+ Ion in the Tetragonal Zn2+ Site of Ba2ZnF6 Crystal.ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES,65(10),877-881. |
| MLA | Li, Bang-Xing,et al."A Study of Spin-Hamiltonian Parameters and Defect Structure for Co2+ Ion in the Tetragonal Zn2+ Site of Ba2ZnF6 Crystal".ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES 65.10(2010):877-881. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment