Synthesis and crystal structure of a novel hexaborate, Na2ZnB6O11

doi:10.1154/1.3309719

IMR OpenIR

	Synthesis and crystal structure of a novel hexaborate, Na2ZnB6O11
	Chen, Y. Q.1; Liang, J. K.1,2; Gu, Y. X.1; Luo, J.1; Li, J. B.1; Rao, G. H.1
通讯作者	Liang, J. K.(jkliang@aphy.iphy.ac.cn)
	2010-03-01
发表期刊	POWDER DIFFRACTION
ISSN	0885-7156
卷号	25 期号:1 页码:9-14
摘要	A novel hexaborate, Na2ZnB6O11, has been successfully synthesized by solid-state reaction and ab initio crystal-structure analysis has been completed using powder X-ray diffraction data. The compound crystallizes in the monoclinic space group Cc with lattice parameters a = 10.7329(2) angstrom, b=7.4080(3) angstrom. c=11.4822(2) angstrom, and beta= 112.16(2)degrees. The number of chemical formula per unit cell is Z=4 and the calculated density is 2.768(3) g/cm(3). It represents a new structure type in which double-bridge-ring [B6O11](4-) groups were found as fundamental building units. The infrared spectrum confirms the presence of both [BO3](3-) groups and [BO4](5-) groups. (C) 2010 International Centre for Diffraction Data. [DOI: 10.1154/1.3309719]
关键词	Na2ZnB6O11 crystal structure powder diffraction hexaborate synthesis
资助者	National Natural Science Foundation of China
DOI	10.1154/1.3309719
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[50672123]
WOS研究方向	Materials Science
WOS类目	Materials Science, Characterization & Testing
WOS记录号	WOS:000275547500004
出版者	J C P D S-INT CENTRE DIFFRACTION DATA
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/100743
专题	中国科学院金属研究所
通讯作者	Liang, J. K.
作者单位	1.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China 2.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Chen, Y. Q.,Liang, J. K.,Gu, Y. X.,et al. Synthesis and crystal structure of a novel hexaborate, Na2ZnB6O11[J]. POWDER DIFFRACTION,2010,25(1):9-14.
APA	Chen, Y. Q.,Liang, J. K.,Gu, Y. X.,Luo, J.,Li, J. B.,&Rao, G. H..(2010).Synthesis and crystal structure of a novel hexaborate, Na2ZnB6O11.POWDER DIFFRACTION,25(1),9-14.
MLA	Chen, Y. Q.,et al."Synthesis and crystal structure of a novel hexaborate, Na2ZnB6O11".POWDER DIFFRACTION 25.1(2010):9-14.