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Effect of Eu substitution on the crystal structure and multiferroic properties of BiFeO3
Zhang, Xingquan1; Sui, Yu1,2; Wang, Xianjie1; Wang, Yang3; Wang, Zhu1
通讯作者Sui, Yu(suiyu@hit.edu.cn)
2010-09-24
发表期刊JOURNAL OF ALLOYS AND COMPOUNDS
ISSN0925-8388
卷号507期号:1页码:157-161
摘要Single-phase Bil(1-x)Eu(x)FeO(3) (0 <= x <= 0.3) multiferroic ceramics were prepared to study the effects of Eu substitution on their crystal structure and ferroelectromagnetic behavior. X-ray diffraction studies revealed a sequence of the composition-driven structural phase transitions R3c -> Pn2(1)alpha (occurs at x = 0.2). Magnetic measurements revealed that Eu substitution can effectively induce the appearance of the spontaneous magnetization, which was significantly enhanced upon the composition-driven transition from a rhombohedral to an orthorhombic phase. The leakage current was found to be reduced on increased Eu concentration. The electric hysteresis loops were obtained in the Bi1-xEuxFeO3 ceramics, but the loops were not really saturated. The magnetoelectric coupling in Eu-doped BiFeO3 was estimated by the changes in the dielectric constant with an external magnetic filed. (C) 2010 Elsevier B.V. All rights reserved.
关键词Multiferroic BiFeO3 Substitution Magnetoelectric coupling
资助者National Natural Science Foundation of China ; Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry ; natural scientific research innovation foundation in Harbin Institute of Technology
DOI10.1016/j.jallcom.2010.07.144
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[50672019] ; National Natural Science Foundation of China[10804024] ; Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry ; natural scientific research innovation foundation in Harbin Institute of Technology[HIT. NSRIF.2009056]
WOS研究方向Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号WOS:000283005300034
出版者ELSEVIER SCIENCE SA
引用统计
被引频次:188[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/100755
专题中国科学院金属研究所
通讯作者Sui, Yu
作者单位1.Harbin Inst Technol, Ctr Condensed Matter Sci & Technol, Dept Phys, Harbin 150001, Peoples R China
2.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
3.Nanyang Technol Univ, Div Phys & Appl Phys, Sch Phys & Math Sci, Singapore 637371, Singapore
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Zhang, Xingquan,Sui, Yu,Wang, Xianjie,et al. Effect of Eu substitution on the crystal structure and multiferroic properties of BiFeO3[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2010,507(1):157-161.
APA Zhang, Xingquan,Sui, Yu,Wang, Xianjie,Wang, Yang,&Wang, Zhu.(2010).Effect of Eu substitution on the crystal structure and multiferroic properties of BiFeO3.JOURNAL OF ALLOYS AND COMPOUNDS,507(1),157-161.
MLA Zhang, Xingquan,et al."Effect of Eu substitution on the crystal structure and multiferroic properties of BiFeO3".JOURNAL OF ALLOYS AND COMPOUNDS 507.1(2010):157-161.
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