| Comparative study of EPR spectra and crystal field effect on local structure for (NiF6)(4-) coordination complex in Ni2+:ZnF2, NiF2, and Ni2+:MgF2 systems | |
| Wang, Su-Juan1; Kuang, Xiao-Yu1,2; Duan, Mei-Ling1; Zhang, Cai-Xia1; Lu, Cheng1 | |
| Corresponding Author | Kuang, Xiao-Yu(scu_wsj@163.com) |
| 2010-02-01 | |
| Source Publication | PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS
 |
| ISSN | 0370-1972 |
| Volume | 247Issue:2Pages:416-421 |
| Abstract | The present work employs the complete energy matrices for a d(8) configuration ion in a D-2h symmetry ligand field at first time to study the relationship between electron paramagnetic resonance (EPR) spectra and local structure of (NiF6)(4-) coordination complex in Ni2+:ZnF2, NiF2, and Ni2+:MgF2 systems, respectively. The crystal field effect on the local structure of the three systems is investigated contrastively by calculating the values of vertical bar partial derivative D'/partial derivative theta vertical bar and vertical bar partial derivative E'/partial derivative theta vertical bar around the (NiF6)(4-) coordination complex. Moreover, the theoretical values of the g factors of Ni2+:ZnF2, NiF2, and Ni2+:MgF2 systems are reported. Simultaneously, the calculated energy levels are in good agreement with the experimental absorption spectra. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
| Funding Organization | National Natural Science Foundation of China ; Education Ministry of China |
| DOI | 10.1002/pssb.200945261 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[10774103] ; Education Ministry of China[20050610011] |
| WOS Research Area | Physics |
| WOS Subject | Physics, Condensed Matter |
| WOS ID | WOS:000274607500029 |
| Publisher | WILEY-BLACKWELL |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/100905 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Kuang, Xiao-Yu |
| Affiliation | 1.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China 2.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Wang, Su-Juan,Kuang, Xiao-Yu,Duan, Mei-Ling,et al. Comparative study of EPR spectra and crystal field effect on local structure for (NiF6)(4-) coordination complex in Ni2+:ZnF2, NiF2, and Ni2+:MgF2 systems[J]. PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS,2010,247(2):416-421. |
| APA | Wang, Su-Juan,Kuang, Xiao-Yu,Duan, Mei-Ling,Zhang, Cai-Xia,&Lu, Cheng.(2010).Comparative study of EPR spectra and crystal field effect on local structure for (NiF6)(4-) coordination complex in Ni2+:ZnF2, NiF2, and Ni2+:MgF2 systems.PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS,247(2),416-421. |
| MLA | Wang, Su-Juan,et al."Comparative study of EPR spectra and crystal field effect on local structure for (NiF6)(4-) coordination complex in Ni2+:ZnF2, NiF2, and Ni2+:MgF2 systems".PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS 247.2(2010):416-421. |
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