Study of local structures and optical spectra for octahedral Fe3+ centers in a series of garnet crystals A(3)B(2)C(3)O(12) (A = Cd, Ca; B = Al, Ga, Sc, In; C = Ge, Si)

doi:10.1016/j.cplett.2009.11.046

IMR OpenIR

	Study of local structures and optical spectra for octahedral Fe3+ centers in a series of garnet crystals A(3)B(2)C(3)O(12) (A = Cd, Ca; B = Al, Ga, Sc, In; C = Ge, Si)
	Li, Hui-Li 1; Kuang, Xiao-Yu 1,2; Mao, Ai-Jie 1; Li, Ying 1; Wang, Su-Juan 1
通讯作者	Kuang, Xiao-Yu(scu_kuang@163.com)
	2010-01-07
发表期刊	CHEMICAL PHYSICS LETTERS
ISSN	0009-2614
卷号	484 期号:4-6 页码:387-391
摘要	Using the unified ligand-field coupling scheme, the local structures and optical spectra of octahedral Fe3+ centers in a series of garnet crystals have been investigated systematically with two different values of parameter A(4). Our results show that the local structures of octahedral Fe3+ centers in doped systems are similar to one another if there are the same external environments around B ions in the host crystals. Being independent of the sign of the spin Hamiltonian parameter b(2)(0), it is increasingly close to zero along with structure parameter R increasing. Moreover, b(2)(0) is almost linear with the change of structure parameter theta. (C) 2009 Elsevier B.V. All rights reserved.
资助者	National Natural Science Foundation of China ; Education Ministry of China
DOI	10.1016/j.cplett.2009.11.046
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[10774103] ; Education Ministry of China[20050610011]
WOS研究方向	Chemistry ; Physics
WOS类目	Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS记录号	WOS:000273051800059
出版者	ELSEVIER SCIENCE BV
引用统计	被引频次：6[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/101054
专题	中国科学院金属研究所
通讯作者	Kuang, Xiao-Yu
作者单位	1.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China 2.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Li, Hui-Li,Kuang, Xiao-Yu,Mao, Ai-Jie,et al. Study of local structures and optical spectra for octahedral Fe3+ centers in a series of garnet crystals A(3)B(2)C(3)O(12) (A = Cd, Ca; B = Al, Ga, Sc, In; C = Ge, Si)[J]. CHEMICAL PHYSICS LETTERS,2010,484(4-6):387-391.
APA	Li, Hui-Li,Kuang, Xiao-Yu,Mao, Ai-Jie,Li, Ying,&Wang, Su-Juan.(2010).Study of local structures and optical spectra for octahedral Fe3+ centers in a series of garnet crystals A(3)B(2)C(3)O(12) (A = Cd, Ca; B = Al, Ga, Sc, In; C = Ge, Si).CHEMICAL PHYSICS LETTERS,484(4-6),387-391.
MLA	Li, Hui-Li,et al."Study of local structures and optical spectra for octahedral Fe3+ centers in a series of garnet crystals A(3)B(2)C(3)O(12) (A = Cd, Ca; B = Al, Ga, Sc, In; C = Ge, Si)".CHEMICAL PHYSICS LETTERS 484.4-6(2010):387-391.