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Study of local structures and optical spectra for octahedral Fe3+ centers in a series of garnet crystals A(3)B(2)C(3)O(12) (A = Cd, Ca; B = Al, Ga, Sc, In; C = Ge, Si)
Li, Hui-Li1; Kuang, Xiao-Yu1,2; Mao, Ai-Jie1; Li, Ying1; Wang, Su-Juan1
Corresponding AuthorKuang, Xiao-Yu(scu_kuang@163.com)
2010-01-07
Source PublicationCHEMICAL PHYSICS LETTERS
ISSN0009-2614
Volume484Issue:4-6Pages:387-391
AbstractUsing the unified ligand-field coupling scheme, the local structures and optical spectra of octahedral Fe3+ centers in a series of garnet crystals have been investigated systematically with two different values of parameter A(4). Our results show that the local structures of octahedral Fe3+ centers in doped systems are similar to one another if there are the same external environments around B ions in the host crystals. Being independent of the sign of the spin Hamiltonian parameter b(2)(0), it is increasingly close to zero along with structure parameter R increasing. Moreover, b(2)(0) is almost linear with the change of structure parameter theta. (C) 2009 Elsevier B.V. All rights reserved.
Funding OrganizationNational Natural Science Foundation of China ; Education Ministry of China
DOI10.1016/j.cplett.2009.11.046
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[10774103] ; Education Ministry of China[20050610011]
WOS Research AreaChemistry ; Physics
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS IDWOS:000273051800059
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/101056
Collection中国科学院金属研究所
Corresponding AuthorKuang, Xiao-Yu
Affiliation1.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China
2.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
Recommended Citation
GB/T 7714
Li, Hui-Li,Kuang, Xiao-Yu,Mao, Ai-Jie,et al. Study of local structures and optical spectra for octahedral Fe3+ centers in a series of garnet crystals A(3)B(2)C(3)O(12) (A = Cd, Ca; B = Al, Ga, Sc, In; C = Ge, Si)[J]. CHEMICAL PHYSICS LETTERS,2010,484(4-6):387-391.
APA Li, Hui-Li,Kuang, Xiao-Yu,Mao, Ai-Jie,Li, Ying,&Wang, Su-Juan.(2010).Study of local structures and optical spectra for octahedral Fe3+ centers in a series of garnet crystals A(3)B(2)C(3)O(12) (A = Cd, Ca; B = Al, Ga, Sc, In; C = Ge, Si).CHEMICAL PHYSICS LETTERS,484(4-6),387-391.
MLA Li, Hui-Li,et al."Study of local structures and optical spectra for octahedral Fe3+ centers in a series of garnet crystals A(3)B(2)C(3)O(12) (A = Cd, Ca; B = Al, Ga, Sc, In; C = Ge, Si)".CHEMICAL PHYSICS LETTERS 484.4-6(2010):387-391.
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