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Improved hydrogen storage properties of LiBH4 by mechanical milling with various carbon additives
Fang, Zhan-Zhao; Kang, Xiang-Dong; Wang, Ping
通讯作者Wang, Ping(pingwang@imr.ac.cn)
2010-08-01
发表期刊INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
ISSN0360-3199
卷号35期号:15页码:8247-8252
摘要Various LiBH4/carbon (graphite (G), purified single-walled carbon nanotubes (SWNTs) and activated carbon (AC)) composites were prepared by mechanical milling method and further examined with respect to their hydrogen storage properties. It was found that all the carbon additives can improve the H-exchange kinetics and H-capacity of LiBH4 to some extents. Compared with G, SWNTs and AC exhibited better promoting effect on the hydrogen storage properties of LiBH4. Based on combined property/phase/structure analysis results, the promoting effect of the carbon additives was largely attributed to their heterogeneous nucleation and micro-confinement effect on the reversible dehydrogenation of LiBH4. (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
关键词Lithium borohydride Carbon additive Mechanical milling Hydrogen storage
DOI10.1016/j.ijhydene.2009.12.037
收录类别SCI
语种英语
WOS研究方向Chemistry ; Electrochemistry ; Energy & Fuels
WOS类目Chemistry, Physical ; Electrochemistry ; Energy & Fuels
WOS记录号WOS:000281383900076
出版者PERGAMON-ELSEVIER SCIENCE LTD
引用统计
被引频次:48[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/101350
专题中国科学院金属研究所
通讯作者Wang, Ping
作者单位Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
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GB/T 7714
Fang, Zhan-Zhao,Kang, Xiang-Dong,Wang, Ping. Improved hydrogen storage properties of LiBH4 by mechanical milling with various carbon additives[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2010,35(15):8247-8252.
APA Fang, Zhan-Zhao,Kang, Xiang-Dong,&Wang, Ping.(2010).Improved hydrogen storage properties of LiBH4 by mechanical milling with various carbon additives.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,35(15),8247-8252.
MLA Fang, Zhan-Zhao,et al."Improved hydrogen storage properties of LiBH4 by mechanical milling with various carbon additives".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 35.15(2010):8247-8252.
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