Improved hydrogen storage properties of LiBH4 by mechanical milling with various carbon additives | |
Fang, Zhan-Zhao; Kang, Xiang-Dong; Wang, Ping | |
通讯作者 | Wang, Ping(pingwang@imr.ac.cn) |
2010-08-01 | |
发表期刊 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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ISSN | 0360-3199 |
卷号 | 35期号:15页码:8247-8252 |
摘要 | Various LiBH4/carbon (graphite (G), purified single-walled carbon nanotubes (SWNTs) and activated carbon (AC)) composites were prepared by mechanical milling method and further examined with respect to their hydrogen storage properties. It was found that all the carbon additives can improve the H-exchange kinetics and H-capacity of LiBH4 to some extents. Compared with G, SWNTs and AC exhibited better promoting effect on the hydrogen storage properties of LiBH4. Based on combined property/phase/structure analysis results, the promoting effect of the carbon additives was largely attributed to their heterogeneous nucleation and micro-confinement effect on the reversible dehydrogenation of LiBH4. (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved. |
关键词 | Lithium borohydride Carbon additive Mechanical milling Hydrogen storage |
DOI | 10.1016/j.ijhydene.2009.12.037 |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels |
WOS类目 | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
WOS记录号 | WOS:000281383900076 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/101350 |
专题 | 中国科学院金属研究所 |
通讯作者 | Wang, Ping |
作者单位 | Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Fang, Zhan-Zhao,Kang, Xiang-Dong,Wang, Ping. Improved hydrogen storage properties of LiBH4 by mechanical milling with various carbon additives[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2010,35(15):8247-8252. |
APA | Fang, Zhan-Zhao,Kang, Xiang-Dong,&Wang, Ping.(2010).Improved hydrogen storage properties of LiBH4 by mechanical milling with various carbon additives.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,35(15),8247-8252. |
MLA | Fang, Zhan-Zhao,et al."Improved hydrogen storage properties of LiBH4 by mechanical milling with various carbon additives".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 35.15(2010):8247-8252. |
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