Theoretical investigation of the optical spectra and local lattice structure for Mn5+ in a Sr-10(VO4)(6)F-2 crystal

doi:10.1080/14786430903321396

IMR OpenIR

	Theoretical investigation of the optical spectra and local lattice structure for Mn5+ in a Sr-10(VO4)(6)F-2 crystal
	Feng, W. L.1,3; Zhong, Y. C.2; Zhang, F.1; Wei, Q.1; Zhang, X. H.1
通讯作者	Feng, W. L.(wenlinfeng@126.com)
	2010
发表期刊	PHILOSOPHICAL MAGAZINE
ISSN	1478-6435
卷号	90 期号:9 页码:1213-1217
摘要	In this paper, the relationships between the optical spectra and local lattice structure for Mn5+ in a Sr-10(VO4)(6)F-2 crystal are established by the crystal- and ligand-field theory. The effect of spin-orbital coupling between the central 3d(2) ions and ligand ions has been considered in the full energy matrix. Using the matrix and superposition model formula, we have calculated the optical spectra and local lattice structure parameters of Mn5+ in Sr-10(VO4)(6)F-2 with a C-3v system. The calculated results are in good agreement with the observed values. In addition, the trigonal compressed distortions of the (MnO4)(3-) centers in Sr-10(VO4)(6)F-2 crystals are also obtained from the calculations.
关键词	optical spectra crystal- and ligand-field theory superposition model Mn5+ Sr-10(VO4)(6)F-2
资助者	foundation of Chongqing University of Technology ; Chongqing Education Committee
DOI	10.1080/14786430903321396
收录类别	SCI
语种	英语
资助项目	foundation of Chongqing University of Technology[2008ZQ12] ; foundation of Chongqing University of Technology[2009ZD09] ; Chongqing Education Committee[KJ090608] ; Chongqing Education Committee[KJ090626]
WOS研究方向	Materials Science ; Mechanics ; Metallurgy & Metallurgical Engineering ; Physics
WOS类目	Materials Science, Multidisciplinary ; Mechanics ; Metallurgy & Metallurgical Engineering ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:000276638300008
出版者	TAYLOR & FRANCIS LTD
引用统计	被引频次：10[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/101860
专题	中国科学院金属研究所
通讯作者	Feng, W. L.
作者单位	1.Chongqing Univ Technol, Dept Appl Phys, Chongqing 400054, Peoples R China 2.Chongqing Univ, Ctr Commun & Tracking Telemetering Command, Chongqing 400044, Peoples R China 3.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Feng, W. L.,Zhong, Y. C.,Zhang, F.,et al. Theoretical investigation of the optical spectra and local lattice structure for Mn5+ in a Sr-10(VO4)(6)F-2 crystal[J]. PHILOSOPHICAL MAGAZINE,2010,90(9):1213-1217.
APA	Feng, W. L.,Zhong, Y. C.,Zhang, F.,Wei, Q.,&Zhang, X. H..(2010).Theoretical investigation of the optical spectra and local lattice structure for Mn5+ in a Sr-10(VO4)(6)F-2 crystal.PHILOSOPHICAL MAGAZINE,90(9),1213-1217.
MLA	Feng, W. L.,et al."Theoretical investigation of the optical spectra and local lattice structure for Mn5+ in a Sr-10(VO4)(6)F-2 crystal".PHILOSOPHICAL MAGAZINE 90.9(2010):1213-1217.