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Investigations of the defect structures and the EPR parameters for the substitutional Mo5+ centers in rutile type crystals
Wu, Shao-Yi1,2; Hu, Yue-Xia1; Wang, Xue-Feng1; Fu, Chuan-Ji1
Corresponding AuthorWu, Shao-Yi(shaoyi_wu@163.com)
2010
Source PublicationRADIATION EFFECTS AND DEFECTS IN SOLIDS
ISSN1042-0150
Volume165Issue:4Pages:298-304
AbstractThe defect structures and the electron paramagnetic resonance parameters for the substitutional Mo5+ centers in rutile type SnO2, TiO2 and GeO2 crystals are theoretically investigated from the perturbation formulas of these parameters for a 4d(1) ion in rhombically compressed octahedra. The [MoO6](7-) clusters suffer the Jahn-Teller effect and transform the ligand octahedra from original elongation on host tetravalent sites to compression in the impurity centers, with additional smaller rhombic (perpendicular) distortions when compared with those in the hosts. The defect structures and the importance of the ligand contributions are discussed.
Keyworddefect structures electron paramagnetic resonance crystal and ligand fields Mo5+ SnO2 TiO2 GeO2
Funding OrganizationSupport Program for Academic Excellence of UESTC
DOI10.1080/10420150903454241
Indexed BySCI
Language英语
Funding ProjectSupport Program for Academic Excellence of UESTC ; [UESTC]
WOS Research AreaNuclear Science & Technology ; Physics
WOS SubjectNuclear Science & Technology ; Physics, Fluids & Plasmas ; Physics, Condensed Matter
WOS IDWOS:000276906200004
PublisherTAYLOR & FRANCIS LTD
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/102282
Collection中国科学院金属研究所
Corresponding AuthorWu, Shao-Yi
Affiliation1.Univ Elect Sci & Technol China, Dept Appl Phys, Chengdu 610054, Peoples R China
2.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
Recommended Citation
GB/T 7714
Wu, Shao-Yi,Hu, Yue-Xia,Wang, Xue-Feng,et al. Investigations of the defect structures and the EPR parameters for the substitutional Mo5+ centers in rutile type crystals[J]. RADIATION EFFECTS AND DEFECTS IN SOLIDS,2010,165(4):298-304.
APA Wu, Shao-Yi,Hu, Yue-Xia,Wang, Xue-Feng,&Fu, Chuan-Ji.(2010).Investigations of the defect structures and the EPR parameters for the substitutional Mo5+ centers in rutile type crystals.RADIATION EFFECTS AND DEFECTS IN SOLIDS,165(4),298-304.
MLA Wu, Shao-Yi,et al."Investigations of the defect structures and the EPR parameters for the substitutional Mo5+ centers in rutile type crystals".RADIATION EFFECTS AND DEFECTS IN SOLIDS 165.4(2010):298-304.
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