| Investigations of the defect structures and the EPR parameters for the substitutional Mo5+ centers in rutile type crystals | |
| Wu, Shao-Yi1,2; Hu, Yue-Xia1; Wang, Xue-Feng1; Fu, Chuan-Ji1 | |
| Corresponding Author | Wu, Shao-Yi(shaoyi_wu@163.com) |
| 2010 | |
| Source Publication | RADIATION EFFECTS AND DEFECTS IN SOLIDS
 |
| ISSN | 1042-0150 |
| Volume | 165Issue:4Pages:298-304 |
| Abstract | The defect structures and the electron paramagnetic resonance parameters for the substitutional Mo5+ centers in rutile type SnO2, TiO2 and GeO2 crystals are theoretically investigated from the perturbation formulas of these parameters for a 4d(1) ion in rhombically compressed octahedra. The [MoO6](7-) clusters suffer the Jahn-Teller effect and transform the ligand octahedra from original elongation on host tetravalent sites to compression in the impurity centers, with additional smaller rhombic (perpendicular) distortions when compared with those in the hosts. The defect structures and the importance of the ligand contributions are discussed. |
| Keyword | defect structures electron paramagnetic resonance crystal and ligand fields Mo5+ SnO2 TiO2 GeO2 |
| Funding Organization | Support Program for Academic Excellence of UESTC |
| DOI | 10.1080/10420150903454241 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Support Program for Academic Excellence of UESTC ; [UESTC] |
| WOS Research Area | Nuclear Science & Technology ; Physics |
| WOS Subject | Nuclear Science & Technology ; Physics, Fluids & Plasmas ; Physics, Condensed Matter |
| WOS ID | WOS:000276906200004 |
| Publisher | TAYLOR & FRANCIS LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/102282 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Wu, Shao-Yi |
| Affiliation | 1.Univ Elect Sci & Technol China, Dept Appl Phys, Chengdu 610054, Peoples R China 2.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Wu, Shao-Yi,Hu, Yue-Xia,Wang, Xue-Feng,et al. Investigations of the defect structures and the EPR parameters for the substitutional Mo5+ centers in rutile type crystals[J]. RADIATION EFFECTS AND DEFECTS IN SOLIDS,2010,165(4):298-304. |
| APA | Wu, Shao-Yi,Hu, Yue-Xia,Wang, Xue-Feng,&Fu, Chuan-Ji.(2010).Investigations of the defect structures and the EPR parameters for the substitutional Mo5+ centers in rutile type crystals.RADIATION EFFECTS AND DEFECTS IN SOLIDS,165(4),298-304. |
| MLA | Wu, Shao-Yi,et al."Investigations of the defect structures and the EPR parameters for the substitutional Mo5+ centers in rutile type crystals".RADIATION EFFECTS AND DEFECTS IN SOLIDS 165.4(2010):298-304. |
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