UV-Induced Oxidative Energy Storage Behavior of a Novel Nanostructured TiO2-Ni(OH)(2) Bilayer System | |
Zhang, Liying1; Xu, Lei1; Wang, Jianming1; Shao, Haibo1; Fan, Yuqian1; Zhang, Jianqing1,2 | |
Corresponding Author | Wang, Jianming(wjm@zju.edu.cn) |
2011-09-15 | |
Source Publication | JOURNAL OF PHYSICAL CHEMISTRY C
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ISSN | 1932-7447 |
Volume | 115Issue:36Pages:18027-18034 |
Abstract | Storage of the oxidative energy generated at a UV-irradiated TiO2 photocatalyst can be achieved by coupling TiO2 with Ni(OH)(2), a redox-active p-type semiconductor. However, improvement on the oxidative energy storage efficiency of the TiO2/Ni(OH)(2) system is becoming a challenge. In this paper, we have investigated the UV-induced oxidative energy storage behavior of a novel nanostructured TiO2-Ni(OH)(2) bilayer system fabricated by the cathodic electrodeposition of a Ni(OH)(2) layer onto an oriented TiO2 nanorod film. The as-prepared bilayer system shows a markedly enhanced apparent quantum yield (6.8%), and the number of the corresponding irradiation-discharge cycles has significantly increased. A possible UV-induced oxidative energy storage mechanism for the bilayer-platinum coupling system is proposed. |
Funding Organization | National Natural Science Foundation of China |
DOI | 10.1021/jp205265e |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Natural Science Foundation of China[50972128] |
WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science |
WOS Subject | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
WOS ID | WOS:000294701600053 |
Publisher | AMER CHEMICAL SOC |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/103779 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Wang, Jianming |
Affiliation | 1.Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China 2.Chinese Acad Sci, Inst Met Res, State Key Lab Corros & Protect Met, Shenyang 110016, Peoples R China |
Recommended Citation GB/T 7714 | Zhang, Liying,Xu, Lei,Wang, Jianming,et al. UV-Induced Oxidative Energy Storage Behavior of a Novel Nanostructured TiO2-Ni(OH)(2) Bilayer System[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2011,115(36):18027-18034. |
APA | Zhang, Liying,Xu, Lei,Wang, Jianming,Shao, Haibo,Fan, Yuqian,&Zhang, Jianqing.(2011).UV-Induced Oxidative Energy Storage Behavior of a Novel Nanostructured TiO2-Ni(OH)(2) Bilayer System.JOURNAL OF PHYSICAL CHEMISTRY C,115(36),18027-18034. |
MLA | Zhang, Liying,et al."UV-Induced Oxidative Energy Storage Behavior of a Novel Nanostructured TiO2-Ni(OH)(2) Bilayer System".JOURNAL OF PHYSICAL CHEMISTRY C 115.36(2011):18027-18034. |
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