Theoretical investigation for the EPR g-factors of the mixed ground state in NaCl: Ag2+ crystals

doi:10.1016/j.saa.2011.04.060

IMR OpenIR

	Theoretical investigation for the EPR g-factors of the mixed ground state in NaCl: Ag2+ crystals
	Li, W. L.1; Li, X. M.1,2; Feng, W. L.1,3,4; Yang, W. J.2; Tao, C. Y.1
通讯作者	Li, X. M.(xuemingli@cqu.edu.cn)
	2011-09-01
发表期刊	SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
ISSN	1386-1425
卷号	79 期号:5 页码:1308-1310
摘要	In this paper, it is considered that the local structure of the (AgCl6)(4-) cluster for the NaCI: Ag2+ crystal is of the axially elongational D-4h symmetry which possesses the weaker rhombic distortion at < 001 > lattice site. The mechanism for an admixture of the (2)A(1g) into the ground state B-2(1g) is taken into account. The electron paramagnetic resonance (EPR)g factors of NaCl: Ag2+ are studied by using the double spin-orbit coupling model and an approximation of a semiempirical molecular orbit. The EPR g factors for the NaCl: Ag2+ crystals are reasonably explained as well as the good agreement between the calculated values and the experimental data is obtained. (C) 2011 Elsevier B.V. All rights reserved.
关键词	Electron paramagnetic resonance Double spin-orbit coupling model NaCl Ag2+
资助者	National Science Foundation for Postdoctoral Scientists of China ; Natural Science Foundation, Education Commission of Chongqing, China ; Fundamental Research Funds for the Central Universities
DOI	10.1016/j.saa.2011.04.060
收录类别	SCI
语种	英语
资助项目	National Science Foundation for Postdoctoral Scientists of China[20100470811] ; Natural Science Foundation, Education Commission of Chongqing, China[KJ090608] ; Fundamental Research Funds for the Central Universities[CDJXS10122217]
WOS研究方向	Spectroscopy
WOS类目	Spectroscopy
WOS记录号	WOS:000293363000068
出版者	PERGAMON-ELSEVIER SCIENCE LTD
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/104461
专题	中国科学院金属研究所
通讯作者	Li, X. M.
作者单位	1.Chongqing Univ, Coll Optoelect Engn, Minist Educ, Key Lab Optoelect Technol & Syst, Chongqing 400044, Peoples R China 2.Chongqing Univ, Coll Chem & Chem Engn, Chongqing 400044, Peoples R China 3.Chongqing Univ Technol, Dept Appl Phys, Chongqing 400054, Peoples R China 4.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Li, W. L.,Li, X. M.,Feng, W. L.,et al. Theoretical investigation for the EPR g-factors of the mixed ground state in NaCl: Ag2+ crystals[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2011,79(5):1308-1310.
APA	Li, W. L.,Li, X. M.,Feng, W. L.,Yang, W. J.,&Tao, C. Y..(2011).Theoretical investigation for the EPR g-factors of the mixed ground state in NaCl: Ag2+ crystals.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,79(5),1308-1310.
MLA	Li, W. L.,et al."Theoretical investigation for the EPR g-factors of the mixed ground state in NaCl: Ag2+ crystals".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 79.5(2011):1308-1310.