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Analysis of Ground-State Zero-Field Splitting for Mn2+ in ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O)
Li Ju-Fen1; Kuang Xiao-Yu2,3
通讯作者Li Ju-Fen()
2011-06-01
发表期刊CHINESE PHYSICS LETTERS
ISSN0256-307X
卷号28期号:6页码:3
摘要The electron paramagnetic resonance spectra of trigonal Mn2+ centers in ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O) crystals are studied on the basis of the complete energy matrices for a d(5) configuration ion in a trigonal ligand field. It is demonstrated that the local lattice structure around a trigonal Mn2+ center has an elongation distortion along the crystalline c(3) axis, and when Mn2+ is doped in the ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O) crystals, there is a similar local distortion. From the EPR calculation, the local lattice structure parameters for trigonal Mn2+ centers in ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O) are determined.
资助者National Natural Science Foundation ; Specialized Research Fund for the Doctoral Program of Higher Education of China
DOI10.1088/0256-307X/28/6/067105
收录类别SCI
语种英语
资助项目National Natural Science Foundation[10374068] ; Specialized Research Fund for the Doctoral Program of Higher Education of China[20050610011]
WOS研究方向Physics
WOS类目Physics, Multidisciplinary
WOS记录号WOS:000291243400063
出版者IOP PUBLISHING LTD
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被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/106218
专题中国科学院金属研究所
通讯作者Li Ju-Fen
作者单位1.SW Petr Univ, Sch Sci, Chengdu 610065, Peoples R China
2.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China
3.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
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Li Ju-Fen,Kuang Xiao-Yu. Analysis of Ground-State Zero-Field Splitting for Mn2+ in ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O)[J]. CHINESE PHYSICS LETTERS,2011,28(6):3.
APA Li Ju-Fen,&Kuang Xiao-Yu.(2011).Analysis of Ground-State Zero-Field Splitting for Mn2+ in ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O).CHINESE PHYSICS LETTERS,28(6),3.
MLA Li Ju-Fen,et al."Analysis of Ground-State Zero-Field Splitting for Mn2+ in ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O)".CHINESE PHYSICS LETTERS 28.6(2011):3.
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