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Seebeck coefficient of Ln (x) Ca1-x MnO3 perovskites in paramagnetic state
Wang, Yang1,2; Sui, Yu2,3; Wang, Xianjie2; Su, Wenhui2,3
通讯作者Wang, Yang(wang_yang@ntu.edu.sg)
2011-07-01
发表期刊APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
ISSN0947-8396
卷号104期号:1页码:135-142
摘要The Seebeck coefficient is a function of carrier concentration and configurational entropy. In this report, we semi-theoretically investigate the Seebeck coefficient of Ln (x) Ca1-x MnO3 (Ln=Rare-earth) perovskites based on the electronic structure of the 3d orbitals of Mn ions, using the developed Heikes model, Boltzmann transport model, and diffusion model. The results show that the Seebeck coefficient of such a strongly correlated electron system in paramagnetic state is remarkably affected by site degeneracy. As temperature decreases, the evolution of the spin and orbital degrees of freedom together with the change in phonon scattering mode describes the Seebeck coefficient behavior satisfactorily. The phonon drag effect at low temperature is also discussed.
资助者National Natural Science Foundation of China
DOI10.1007/s00339-010-6081-6
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[50672019] ; National Natural Science Foundation of China[10804024]
WOS研究方向Materials Science ; Physics
WOS类目Materials Science, Multidisciplinary ; Physics, Applied
WOS记录号WOS:000291652600020
出版者SPRINGER
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/106492
专题中国科学院金属研究所
通讯作者Wang, Yang
作者单位1.Nanyang Technol Univ, Div Phys & Appl Phys, Sch Phys & Math Sci, Singapore 637371, Singapore
2.Harbin Inst Technol, Ctr Condensed Matter Sci & Technol CCMST, Dept Phys, Harbin 150001, Peoples R China
3.Acad Sinica, Int Ctr Mat Phys, Shenyang 110015, Peoples R China
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Wang, Yang,Sui, Yu,Wang, Xianjie,et al. Seebeck coefficient of Ln (x) Ca1-x MnO3 perovskites in paramagnetic state[J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING,2011,104(1):135-142.
APA Wang, Yang,Sui, Yu,Wang, Xianjie,&Su, Wenhui.(2011).Seebeck coefficient of Ln (x) Ca1-x MnO3 perovskites in paramagnetic state.APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING,104(1),135-142.
MLA Wang, Yang,et al."Seebeck coefficient of Ln (x) Ca1-x MnO3 perovskites in paramagnetic state".APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING 104.1(2011):135-142.
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