Crystallographic and magnetic properties of hydride R3Fe29-xTxHy (R=Y, Ce, Nd, Sm, Gd, Tb and Dy; T=V and Cr) | |
Han, XF; Lin, LY; Baggio-Saitovitch, E; Xu, RG; Wang, XH; Pan, HG | |
通讯作者 | Han, XF() |
1999 | |
发表期刊 | MAGNETISM, MAGNETIC MATERIALS AND THEIR APPLICATIONS
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ISSN | 0255-5476 |
卷号 | 302-3页码:294-298 |
摘要 | The crystallographic and intrinsic magnetic properties of hydride R3Fe29-xTxHy (R=Y, Ce, Nd, Sm, Gd, Tb, and Dy; T=V and Cr) have been investigated. The lattice constants and the unit cell volume of R3Fe29-xTxHy decrease with increasing R atomic number from Nd to Dy, except for Ce, reflecting the lanthanide contraction. Regular anisotropic expansions, mainly along the a- and b-axis rather than along the c-axis, are observed for all the compounds upon hydrogenation. Hydrogenation leads to an increase in Curie temperature. First-order magnetization processes (FOMP) occur in magnetic fields of around 1.5 T and 4.0 T at 4.2 K for Nd3Fe24.5Cr4.5H5.0 and Tb(3)Fc(27.0)Cr(2.0)H(2.8), and around 1.4 T at room temperature for Gd3Fe28.0Cr1.0H4.2 Abnormal crystallographic and magnetic properties of Ce3Fe29-xTxHy suggest that the Ce ion is non-triply ionized. |
关键词 | magnetic properties hydride hydrogenation saturation magnetization curie temperature first-order magnetization process R3Fe29-xTxHy |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Materials Science ; Physics |
WOS类目 | Materials Science, Multidisciplinary ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter |
WOS记录号 | WOS:000081205300046 |
出版者 | TRANSTEC PUBLICATIONS LTD |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/109863 |
专题 | 中国科学院金属研究所 |
通讯作者 | Han, XF |
作者单位 | 1.Chinese Acad Sci, Inst Semicond, Ctr Mat Sci, Beijing 100083, Peoples R China 2.Ctr Brasileiro Pesquisas Fis, Rio De Janeiro, Brazil 3.Zhejiang Univ, Dept Mat, Hangzhou 310027, Peoples R China |
推荐引用方式 GB/T 7714 | Han, XF,Lin, LY,Baggio-Saitovitch, E,et al. Crystallographic and magnetic properties of hydride R3Fe29-xTxHy (R=Y, Ce, Nd, Sm, Gd, Tb and Dy; T=V and Cr)[J]. MAGNETISM, MAGNETIC MATERIALS AND THEIR APPLICATIONS,1999,302-3:294-298. |
APA | Han, XF,Lin, LY,Baggio-Saitovitch, E,Xu, RG,Wang, XH,&Pan, HG.(1999).Crystallographic and magnetic properties of hydride R3Fe29-xTxHy (R=Y, Ce, Nd, Sm, Gd, Tb and Dy; T=V and Cr).MAGNETISM, MAGNETIC MATERIALS AND THEIR APPLICATIONS,302-3,294-298. |
MLA | Han, XF,et al."Crystallographic and magnetic properties of hydride R3Fe29-xTxHy (R=Y, Ce, Nd, Sm, Gd, Tb and Dy; T=V and Cr)".MAGNETISM, MAGNETIC MATERIALS AND THEIR APPLICATIONS 302-3(1999):294-298. |
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