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Electro catalytic activity for oxygen evolution of titanium based IrO2+Ta2O5 anodes
Hu, JM; Meng, HM; Zhang, JQ; Wu, JX; Yang, DJ; Ca, CN
通讯作者Hu, JM()
2001-06-18
发表期刊ACTA METALLURGICA SINICA
ISSN0412-1961
卷号37期号:6页码:628-632
摘要The electrocatalytic activity of titanium based IrO2+Ta2O5 anodes for oxygen evolution has been investigated by polarization and electrochemical impedance spectroscopy (EIS) techniques. It was shown that the mixed oxide anodes exhibited the highest activity at 70% (mole fraction) IrO2 content. Th-is result was interpreted by the maximum surface concentration of active component IrO2 with the corresponding composition and by the most significant increase of the amount of surface active site after attacking by the evaluated oxygen. Accordingly, the thermodynamic and kinetic criterions determining the electrocatalytic activity of oxide anodes for oxygen evolution have been proposed.
关键词oxide anode IrO2 Ta2O5 oxygen evolution electrocatalytic activity
收录类别SCI
语种英语
WOS研究方向Metallurgy & Metallurgical Engineering
WOS类目Metallurgy & Metallurgical Engineering
WOS记录号WOS:000172766900013
出版者SCIENCE CHINA PRESS
引用统计
被引频次:13[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/112795
专题中国科学院金属研究所
通讯作者Hu, JM
作者单位1.Zhejiang Univ, Dept Chem, Electrochem Lab, Hangzhou 310027, Peoples R China
2.Univ Sci & Technol Beijing, Beijing Corros & Protect Ctr, Beijing 100083, Peoples R China
3.Chinese Acad Sci, Inst Met Res, State Key Lab Corros & Protect, Shenyang 110016, Peoples R China
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GB/T 7714
Hu, JM,Meng, HM,Zhang, JQ,et al. Electro catalytic activity for oxygen evolution of titanium based IrO2+Ta2O5 anodes[J]. ACTA METALLURGICA SINICA,2001,37(6):628-632.
APA Hu, JM,Meng, HM,Zhang, JQ,Wu, JX,Yang, DJ,&Ca, CN.(2001).Electro catalytic activity for oxygen evolution of titanium based IrO2+Ta2O5 anodes.ACTA METALLURGICA SINICA,37(6),628-632.
MLA Hu, JM,et al."Electro catalytic activity for oxygen evolution of titanium based IrO2+Ta2O5 anodes".ACTA METALLURGICA SINICA 37.6(2001):628-632.
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