Electrochemical behavior of amorphous alloy Zr55Al10Cu30Ni5 in 3.5%NaCl solution | |
Wang, C; Zhang, QS; Jiang, F; Zhang, HF; Hu, ZQ | |
Corresponding Author | Wang, C() |
2002-07-01 | |
Source Publication | ACTA METALLURGICA SINICA
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ISSN | 0412-1961 |
Volume | 38Issue:7Pages:765-769 |
Abstract | Corrosion behavior of Zr55Al10CU30Ni5 amorphous alloy in 3.5%NaCl solution was studied by potentiodynamic polarization experiments and electrochemical impedance spectroscopy (EIS). The potentiodynamic polarization experiments showed that the amorphous alloy has a high corrosion resistance in 3.5%NaCl solution and its anodic reaction has a passive characteristic. The amorphous alloy happened pitting corrosion when the applied polarization potential was higher than the pitting corrosion potential. EIS experimental results showed that amorphous alloy has very high charge transfer reaction resistance when the alloy was in the states of cathodic polarization, open circuit potential (OCP) and passive potential, and the EIS consisted of only single large semi-circles, manifesting a high corrosion resistance. When the alloy was in the states of the vicinal zone of pitting and pitting corrosion zone, its EIS consisted of two and three time constants respectively. When the alloy was immersed in 3.5%NaCl solution for about 12h, its corrosion resistance decreased greatly. |
Keyword | Zr-Al-Cu-Ni amorphous alloy electrochemistry EIS corrosion behavior |
Indexed By | SCI |
Language | 英语 |
WOS Research Area | Metallurgy & Metallurgical Engineering |
WOS Subject | Metallurgy & Metallurgical Engineering |
WOS ID | WOS:000177354700020 |
Publisher | SCIENCE CHINA PRESS |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/114670 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Wang, C |
Affiliation | 1.Chinese Acad Sci, Inst Met Res, State Key Lab Corros & Protect Met, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
Recommended Citation GB/T 7714 | Wang, C,Zhang, QS,Jiang, F,et al. Electrochemical behavior of amorphous alloy Zr55Al10Cu30Ni5 in 3.5%NaCl solution[J]. ACTA METALLURGICA SINICA,2002,38(7):765-769. |
APA | Wang, C,Zhang, QS,Jiang, F,Zhang, HF,&Hu, ZQ.(2002).Electrochemical behavior of amorphous alloy Zr55Al10Cu30Ni5 in 3.5%NaCl solution.ACTA METALLURGICA SINICA,38(7),765-769. |
MLA | Wang, C,et al."Electrochemical behavior of amorphous alloy Zr55Al10Cu30Ni5 in 3.5%NaCl solution".ACTA METALLURGICA SINICA 38.7(2002):765-769. |
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