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Formation of passive film on 304 stainless steel under alternating voltage electric field
Zhang, JX; Yan, LC; Wei, ZF; Qiao, YN; Cao, CN; Zhang, JQ
通讯作者Zhang, JX(Zhangjunxi@21cn.com)
2004-04-01
发表期刊ACTA METALLURGICA SINICA
ISSN0412-1961
卷号40期号:4页码:404-410
摘要An investigation on the growth of passive film on 304 stainless steel by using alternating voltage (A.V.) passivation was carried out by electrochemical impedance spectroscopy (EIS), coulometry measurement and atomic force microscopy (AFM). EIS was performed on 304 stainless steel electrode, which is covered by A.V. passive film, to identify the formation of pore as a function of higher potential parts (Eh) in alternating square wave electric field. Coulomb-time curves were measured during the growth of passive film on different conditions. A new concept, probability of pore formation, which describes the behaviour of the pores during the growth of film, was presented. Results indicate that the growth mechanism of A.V. passive film is different from that of D.C. passive film, which makes the AV. passive films have a faster growth rate. Coulomb-time curves and AFM analysis confirmed the growth mechanism of A.V. passive film.
关键词stainless steel alternating voltage passivation growth mechanism probability of pore formation
收录类别SCI
语种英语
WOS研究方向Metallurgy & Metallurgical Engineering
WOS类目Metallurgy & Metallurgical Engineering
WOS记录号WOS:000221112500015
出版者SCIENCE CHINA PRESS
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/119049
专题中国科学院金属研究所
通讯作者Zhang, JX
作者单位1.Shanghai Univ Elect Power, Electrochem Res Grp, Key Lab State Power Corp China, Shanghai 200090, Peoples R China
2.Hangzhou Teachers Coll, Hangzhou 310036, Peoples R China
3.Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
4.Chinese Acad Sci, Inst Met Res, State Key Lab Corros & Protect, Shenyang 110016, Peoples R China
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GB/T 7714
Zhang, JX,Yan, LC,Wei, ZF,et al. Formation of passive film on 304 stainless steel under alternating voltage electric field[J]. ACTA METALLURGICA SINICA,2004,40(4):404-410.
APA Zhang, JX,Yan, LC,Wei, ZF,Qiao, YN,Cao, CN,&Zhang, JQ.(2004).Formation of passive film on 304 stainless steel under alternating voltage electric field.ACTA METALLURGICA SINICA,40(4),404-410.
MLA Zhang, JX,et al."Formation of passive film on 304 stainless steel under alternating voltage electric field".ACTA METALLURGICA SINICA 40.4(2004):404-410.
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