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Dissolution Equilibrium of Iron Vapour and Activities of Iron in Liquid Uranium-Iron Solutions
Chen Bo1; Duan Yujie1; Du Zhanhui1; Liu Kui1; Zhang Xinjian2; Wang Zhenhong2
Corresponding AuthorChen Bo(bchen@imr.ac.cn)
2015-11-01
Source PublicationRARE METAL MATERIALS AND ENGINEERING
ISSN1002-185X
Volume44Issue:11Pages:2793-2797
AbstractA carrier method was used to measure the dissolution equilibrium of iron vapour over liquid U-Fe alloys from 15,00 to 1600 degrees C, and then the activities as well as activity coefficients of iron in liquid U-Fe alloys were calculated from the results for iron. It is found that iron shows strong negative deviation from Raoult's law, and the relationship between the standard free energy of,dissolution reaction Fe-(g)[Fe](Y) and temperature is Delta G(0) =-448682+125.4T. At 1500 and 1600 degrees C, the activity coefficients gamma of iron at infinite dilution are 0.344 and 0.485, respectively.
KeywordU-Fe melt partial vapour pressure of iron activities activity coefficients standard free energy of reaction Delta G(0)
Indexed BySCI
Language英语
WOS Research AreaMaterials Science ; Metallurgy & Metallurgical Engineering
WOS SubjectMaterials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS IDWOS:000365830000038
PublisherNORTHWEST INST NONFERROUS METAL RESEARCH
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/121267
Collection中国科学院金属研究所
Corresponding AuthorChen Bo
Affiliation1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
2.China Acad Engn Phys, Mianyang 621900, Peoples R China
Recommended Citation
GB/T 7714
Chen Bo,Duan Yujie,Du Zhanhui,et al. Dissolution Equilibrium of Iron Vapour and Activities of Iron in Liquid Uranium-Iron Solutions[J]. RARE METAL MATERIALS AND ENGINEERING,2015,44(11):2793-2797.
APA Chen Bo,Duan Yujie,Du Zhanhui,Liu Kui,Zhang Xinjian,&Wang Zhenhong.(2015).Dissolution Equilibrium of Iron Vapour and Activities of Iron in Liquid Uranium-Iron Solutions.RARE METAL MATERIALS AND ENGINEERING,44(11),2793-2797.
MLA Chen Bo,et al."Dissolution Equilibrium of Iron Vapour and Activities of Iron in Liquid Uranium-Iron Solutions".RARE METAL MATERIALS AND ENGINEERING 44.11(2015):2793-2797.
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