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Dissolution Equilibrium of Iron Vapour and Activities of Iron in Liquid Uranium-Iron Solutions
Chen Bo1; Duan Yujie1; Du Zhanhui1; Liu Kui1; Zhang Xinjian2; Wang Zhenhong2
通讯作者Chen Bo(bchen@imr.ac.cn)
2015-11-01
发表期刊RARE METAL MATERIALS AND ENGINEERING
ISSN1002-185X
卷号44期号:11页码:2793-2797
摘要A carrier method was used to measure the dissolution equilibrium of iron vapour over liquid U-Fe alloys from 15,00 to 1600 degrees C, and then the activities as well as activity coefficients of iron in liquid U-Fe alloys were calculated from the results for iron. It is found that iron shows strong negative deviation from Raoult's law, and the relationship between the standard free energy of,dissolution reaction Fe-(g)[Fe](Y) and temperature is Delta G(0) =-448682+125.4T. At 1500 and 1600 degrees C, the activity coefficients gamma of iron at infinite dilution are 0.344 and 0.485, respectively.
关键词U-Fe melt partial vapour pressure of iron activities activity coefficients standard free energy of reaction Delta G(0)
收录类别SCI
语种英语
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号WOS:000365830000038
出版者NORTHWEST INST NONFERROUS METAL RESEARCH
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/121267
专题中国科学院金属研究所
通讯作者Chen Bo
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
2.China Acad Engn Phys, Mianyang 621900, Peoples R China
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GB/T 7714
Chen Bo,Duan Yujie,Du Zhanhui,et al. Dissolution Equilibrium of Iron Vapour and Activities of Iron in Liquid Uranium-Iron Solutions[J]. RARE METAL MATERIALS AND ENGINEERING,2015,44(11):2793-2797.
APA Chen Bo,Duan Yujie,Du Zhanhui,Liu Kui,Zhang Xinjian,&Wang Zhenhong.(2015).Dissolution Equilibrium of Iron Vapour and Activities of Iron in Liquid Uranium-Iron Solutions.RARE METAL MATERIALS AND ENGINEERING,44(11),2793-2797.
MLA Chen Bo,et al."Dissolution Equilibrium of Iron Vapour and Activities of Iron in Liquid Uranium-Iron Solutions".RARE METAL MATERIALS AND ENGINEERING 44.11(2015):2793-2797.
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