X-Ray Photoelectron Spectroscopy of Chlorometallate Ionic Liquids: Speciation and Anion Basicity

doi:10.1007/s10812-018-0611-y

IMR OpenIR

	X-Ray Photoelectron Spectroscopy of Chlorometallate Ionic Liquids: Speciation and Anion Basicity
	Men, Sh.1,2; Jiang, J.3
通讯作者	Men, Sh.(menshuang@hotmail.com)
	2018-03-01
发表期刊	JOURNAL OF APPLIED SPECTROSCOPY
ISSN	0021-9037
卷号	85 期号:1 页码:55-60
摘要	X-ray photoelectron spectroscopy is used to detect the formation of different chlorometallate anions and to differentiate the electronic environment of each element present in chlorometallate anions. The impact of the degree of the charge delocalization of chlorometallate anions on the Cl 2p binding energy is demonstrated in detail. The basicity of chlorostannate and chloroferrate anions is estimated based upon the measured N 1s binding energy. It is found that chlorostannate and chloroferrate anions can be considered as the least basic anions.
关键词	X-ray photoelectron spectroscopy chlorometallate ionic liquids basicity
资助者	General project of Science and Technology Research Project of Liaoning Provincial Department of Education ; China Postdoctoral Science Foundation ; National Science Foundation ; Shenyang Ligong University for the award of an Open Fund of the Key Discipline for Materials Processing Engineering
DOI	10.1007/s10812-018-0611-y
收录类别	SCI
语种	英语
资助项目	General project of Science and Technology Research Project of Liaoning Provincial Department of Education[L2015461] ; China Postdoctoral Science Foundation[2015M571344] ; National Science Foundation[51503007] ; Shenyang Ligong University for the award of an Open Fund of the Key Discipline for Materials Processing Engineering[4771004kfx18]
WOS研究方向	Spectroscopy
WOS类目	Spectroscopy
WOS记录号	WOS:000430006000009
出版者	SPRINGER
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/127801
专题	中国科学院金属研究所
通讯作者	Men, Sh.
作者单位	1.Shenyang Ligong Univ, Sch Mat Sci & Engn, Shenyang 110159, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst Appl Ecol, Shenyang, Liaoning, Peoples R China 3.Northeastern Univ, Sch Mech Engn & Automat, Shenyang, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Men, Sh.,Jiang, J.. X-Ray Photoelectron Spectroscopy of Chlorometallate Ionic Liquids: Speciation and Anion Basicity[J]. JOURNAL OF APPLIED SPECTROSCOPY,2018,85(1):55-60.
APA	Men, Sh.,&Jiang, J..(2018).X-Ray Photoelectron Spectroscopy of Chlorometallate Ionic Liquids: Speciation and Anion Basicity.JOURNAL OF APPLIED SPECTROSCOPY,85(1),55-60.
MLA	Men, Sh.,et al."X-Ray Photoelectron Spectroscopy of Chlorometallate Ionic Liquids: Speciation and Anion Basicity".JOURNAL OF APPLIED SPECTROSCOPY 85.1(2018):55-60.