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Palladium nanoparticles supported on amine-functionalized glass fiber mat for fixed-bed reactors on the effective removal of hexavalent chromium by catalytic reduction
Gao, Yu1,2; Sun, Wuzhu1,3; Yang, Weiyi1; Li, Qi1
通讯作者Li, Qi(qili@imr.ac.cn)
2018-06-01
发表期刊JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN1005-0302
卷号34期号:6页码:961-968
摘要Palladium nanoparticles were deposited on the amine-grafted glass fiber mat ( GFM-NH2) catalyst support by a conventional impregnation process followed by the borohydride reduction in aqueous solution at room temperature to create the designed PcI/GFM-NH2 catalyst. By the use of large size glass fiber mat without nano/mesopores as the catalyst support, the internal mass transfer limitations due to the existence of nano/mesopores on the catalyst support were eliminated and the PcI/GFM-NH2 catalyst could be easily separated from treated water due to the large size of the catalyst support. Batch experiments demonstrate its good catalytic reduction performance of Cr(VI) with formic acid as the reducing agent. It also demonstrated an efficient Cr(VI) removal and stability in a lab-prepared, packed fixed-bed tube reactor for the continuous treatment of Cr(VI)-containing water. Thus, it has a good potential for the catalytic reduction of Cr(VI) in the water treatment practice. (C) 2017 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
关键词Palladium nanoparticle Amine-functionalized glass fiber mat Fixed-bed reactor Hexavalent chromium Catalytic reduction
资助者Shenyang National Laboratory for Materials Science ; National Natural Science Foundation of China
DOI10.1016/j.jmst.2017.05.013
收录类别SCI
语种英语
资助项目Shenyang National Laboratory for Materials Science[Y4N56R1161] ; Shenyang National Laboratory for Materials Science[Y4N56F2161] ; National Natural Science Foundation of China[51502305]
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号WOS:000432686600008
出版者JOURNAL MATER SCI TECHNOL
引用统计
被引频次:26[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/128245
专题中国科学院金属研究所
通讯作者Li, Qi
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Environm Funct Mat Div, Shenyang 110016, Liaoning, Peoples R China
2.China Acad Engn Phys, Inst Mat, Mianyang 621900, Peoples R China
3.Shandong Univ Technol, Sch Mat Sci & Engn, Zibo 255000, Peoples R China
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Gao, Yu,Sun, Wuzhu,Yang, Weiyi,et al. Palladium nanoparticles supported on amine-functionalized glass fiber mat for fixed-bed reactors on the effective removal of hexavalent chromium by catalytic reduction[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2018,34(6):961-968.
APA Gao, Yu,Sun, Wuzhu,Yang, Weiyi,&Li, Qi.(2018).Palladium nanoparticles supported on amine-functionalized glass fiber mat for fixed-bed reactors on the effective removal of hexavalent chromium by catalytic reduction.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,34(6),961-968.
MLA Gao, Yu,et al."Palladium nanoparticles supported on amine-functionalized glass fiber mat for fixed-bed reactors on the effective removal of hexavalent chromium by catalytic reduction".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 34.6(2018):961-968.
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