Fabrication of ultrafine ZnFe2O4 nanoparticles for efficient photocatalytic reduction CO2 under visible light illumination | |
Xiao, Jun1,2; Yang, Weiyi1; Gao, Shuang3; Sun, Caixia4,5; Li, Qi1 | |
通讯作者 | Li, Qi(qili@imr.ac.cn) |
2018-12-01 | |
发表期刊 | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
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ISSN | 1005-0302 |
卷号 | 34期号:12页码:2331-2336 |
摘要 | A one-pot, solvent-thermal process was used to create the ultrafine ZnFe2O4 nanoparticles photocatalyst. During the solvent-thermal process, the in situ self-forming NaCl not only served as a "cage" to confine the ion diffusion, but also acted as a microreactor for nanocrystallite growth. An average particle size of similar to 10 nm and a high-specific surface area of similar to 112.9 m(2)/g were observed for the ultrafine ZnFe2O4 nanoparticles Owing to the synergistic effect of ultrafine particle size, the full utilization of the visible light region and high conduction band (CB) position, ultrafine ZnFe2O4 photocatalyst displayed an efficient photocatalytic CO2 reduction under visible light illumination. Besides, the ultrafine ZnFe2O4 photocatalyst showed high production selectivity for CH3CHO and C2H5OH generation in aqueous CO2/NaHCO3 solution. This work may provide a new idea for the synthesis of new high-efficiency photocatalysts. (C) 2018 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology. |
关键词 | Ultrafine nanoparticles Photocatalytic CO2 reduction Visible light ZnFe2O4 photocatalyst In situ self-formed "cage" |
资助者 | National Natural Science Foundation of China ; Basic Science Innovation Program of Shenyang National Laboratory for Materials Science ; Natural Science Foundation of Shandong Province, China |
DOI | 10.1016/j.jmst.2018.06.001 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[51672283] ; National Natural Science Foundation of China[51602316] ; Basic Science Innovation Program of Shenyang National Laboratory for Materials Science[Y4N56R1161] ; Basic Science Innovation Program of Shenyang National Laboratory for Materials Science[Y5N56F2161] ; Natural Science Foundation of Shandong Province, China[ZR2017MEM017] |
WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
WOS类目 | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
WOS记录号 | WOS:000443274500014 |
出版者 | JOURNAL MATER SCI TECHNOL |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/129330 |
专题 | 中国科学院金属研究所 |
通讯作者 | Li, Qi |
作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Environm Funct Mat Div, Shenyang 110016, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Tsinghua Univ, Grad Sch Shenzhen, Div Energy & Environm, Shenzhen 518055, Peoples R China 4.Qingdao Binhai Univ, Key Lab New Metall Funct Mat & Adv Surface Engn U, Qingdao 266555, Peoples R China 5.Qingdao Binhai Univ, Sch Mech & Elect Engn, Qingdao 266555, Peoples R China |
推荐引用方式 GB/T 7714 | Xiao, Jun,Yang, Weiyi,Gao, Shuang,et al. Fabrication of ultrafine ZnFe2O4 nanoparticles for efficient photocatalytic reduction CO2 under visible light illumination[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2018,34(12):2331-2336. |
APA | Xiao, Jun,Yang, Weiyi,Gao, Shuang,Sun, Caixia,&Li, Qi.(2018).Fabrication of ultrafine ZnFe2O4 nanoparticles for efficient photocatalytic reduction CO2 under visible light illumination.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,34(12),2331-2336. |
MLA | Xiao, Jun,et al."Fabrication of ultrafine ZnFe2O4 nanoparticles for efficient photocatalytic reduction CO2 under visible light illumination".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 34.12(2018):2331-2336. |
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