IMR OpenIR
Metal-Organic Frameworks (MOFs)-Derived Nitrogen-Doped Porous Carbon Anchored on Graphene with Multifunctional Effects for Lithium-Sulfur Batteries
Chen, Ke1,2; Sun, Zhenhua1,3; Fang, Ruopian1; Shi, Ying1; Cheng, Hui-Ming1,2,4; Li, Feng1,3
Corresponding AuthorSun, Zhenhua(zhsun@imr.ac.cn) ; Li, Feng(fli@imr.ac.cn)
2018-09-19
Source PublicationADVANCED FUNCTIONAL MATERIALS
ISSN1616-301X
Volume28Issue:38Pages:8
AbstractLithium-sulfur (Li-S) batteries are highly appealing for next-generation electrochemical energy storage owing to their high theoretical energy density, environmental friendliness, and low cost. However, the insulating nature of sulfur and migration of dissolved polysulfide intermediates lead to low active material utilization and fast capacity decay, which pose a significant challenge to their practical applications. Here, this paper reports a multifunctional carbon hybrid with metal-organic frameworks (MOFs)-derived nitrogen-doped porous carbon anchored on graphene sheets (NPC/G) serving as a sulfur host. On the one hand, the high surface area and nitrogen-doping of the carbon nanoparticles enable effective polysulfide immobilization through both physical confinement and chemical adsorption; on the other hand, the highly conductive graphene provides an interconnected conductive framework to facilitate fast electron transport, improving the sulfur utilization. As a result, the NPC/G-based sulfur cathode exhibits a high specific capacity of 1372 mAh g(-1) with good cycling stability over 300 cycles. This approach provides a promising approach for the design of MOFs-derived carbon materials for high performance Li-S batteries.
Keywordgraphene lithium-sulfur batteries metal-organic frameworks nitrogen doping porous carbon
Funding OrganizationNational Key R&D Program of China ; National Science Foundation of China ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Institute of Metal Research ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Key Research Program of the Chinese Academy of Sciences ; CAS/SAFEA International Partnership Program for Creative Research Teams
DOI10.1002/adfm.201707592
Indexed BySCI
Language英语
Funding ProjectNational Key R&D Program of China[2016YFA0200100] ; National Key R&D Program of China[2016YFB0100100] ; National Key R&D Program of China[2014CB932402] ; National Science Foundation of China[51525206] ; National Science Foundation of China[51521091] ; National Science Foundation of China[U1401243] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[2015150] ; Institute of Metal Research[2015-PY03] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA09010104] ; Key Research Program of the Chinese Academy of Sciences[KGZD-EW-T06] ; CAS/SAFEA International Partnership Program for Creative Research Teams
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:000444672000011
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:169[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/129494
Collection中国科学院金属研究所
Corresponding AuthorSun, Zhenhua; Li, Feng
Affiliation1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
2.Shanghai Tech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
3.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China
4.Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst, Shenzhen 518055, Peoples R China
Recommended Citation
GB/T 7714
Chen, Ke,Sun, Zhenhua,Fang, Ruopian,et al. Metal-Organic Frameworks (MOFs)-Derived Nitrogen-Doped Porous Carbon Anchored on Graphene with Multifunctional Effects for Lithium-Sulfur Batteries[J]. ADVANCED FUNCTIONAL MATERIALS,2018,28(38):8.
APA Chen, Ke,Sun, Zhenhua,Fang, Ruopian,Shi, Ying,Cheng, Hui-Ming,&Li, Feng.(2018).Metal-Organic Frameworks (MOFs)-Derived Nitrogen-Doped Porous Carbon Anchored on Graphene with Multifunctional Effects for Lithium-Sulfur Batteries.ADVANCED FUNCTIONAL MATERIALS,28(38),8.
MLA Chen, Ke,et al."Metal-Organic Frameworks (MOFs)-Derived Nitrogen-Doped Porous Carbon Anchored on Graphene with Multifunctional Effects for Lithium-Sulfur Batteries".ADVANCED FUNCTIONAL MATERIALS 28.38(2018):8.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Chen, Ke]'s Articles
[Sun, Zhenhua]'s Articles
[Fang, Ruopian]'s Articles
Baidu academic
Similar articles in Baidu academic
[Chen, Ke]'s Articles
[Sun, Zhenhua]'s Articles
[Fang, Ruopian]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Chen, Ke]'s Articles
[Sun, Zhenhua]'s Articles
[Fang, Ruopian]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.