| Catalysis by hybrid sp(2)/sp(3) nanodiamonds and their role in the design of advanced nanocarbon materials | |
| Lin, Yangming1,2; Sun, Xiaoyan2; Su, Dang Sheng2,3; Centi, Gabriele4,5; Perathoner, Siglinda6 | |
| Corresponding Author | Lin, Yangming(yang-ming.lin@cec.mpg.de) ; Su, Dang Sheng(dssu@dicp.ac.cn) ; Perathoner, Siglinda(perathon@unime.it) |
| 2018-11-21 | |
| Source Publication | CHEMICAL SOCIETY REVIEWS
 |
| ISSN | 0306-0012 |
| Volume | 47Issue:22Pages:8438-8473 |
| Abstract | Hybrid sp(2)/sp(3) nanocarbons, in particular sp(3)-hybridized ultra-dispersed nanodiamonds and derivative materials, such as the sp(3)/sp(2)-hybridized bucky nanodiamonds and sp(2)-hybridized onion-like carbons, represent a rather interesting class of catalysts still under consideration. Their characteristics, properties and catalytic reactivity are presented, with an analysis of the state-of-the-art of their use in gas- and liquid-phase reactions, including photo- and electro-catalysis. It is remarked that intrinsic differences exist between these and other nanostructured carbon catalysts. The analysis shows how different features make nanocarbons unique with respect to other types of catalysts and are the bases for an advanced design of nanocarbon-type catalysts. The aspects discussed regard the presence of hybrid sp(2)/sp(3) configurations, nano-engineering related to the role of defects and vacancies in their catalytic behaviour, the creation of active sites by modification in the charge density at carbon atoms or C-C bonds, the generation of strained C-C bonds by curvature and other mechanisms, and the formation of semiconducting areas and defect sites at the interface with supported nanoparticles. The advanced strategies for identifying and quantifying active sites of carbon catalysts are highlighted. |
| Funding Organization | Strategic Priority Research Program of the Chinese Academy of Sciences ; Italian MIUR through the PRIN Project ; Max Planck Society |
| DOI | 10.1039/c8cs00684a |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Strategic Priority Research Program of the Chinese Academy of Sciences[XDA09030103] ; Italian MIUR through the PRIN Project[2015K7FZLH SMARTNESS] ; Max Planck Society |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000449968700008 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/130250 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Lin, Yangming; Su, Dang Sheng; Perathoner, Siglinda |
| Affiliation | 1.Max Planck Inst Chem Energiekonvers, Stiftstr 34-36, D-45470 Mulheim, Germany 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian, Peoples R China 4.Univ Messina, ERIC Aisbl, Vle F Stagno DAlcontres 31, I-98166 Messina, Italy 5.CASPE INSTM, Depts MIFT Ind Chem, Vle F Stagno DAlcontres 31, I-98166 Messina, Italy 6.Univ Messina, Depts ChiBioFarAm Ind Chem, Vle F Stagno DAlcontres 31, I-98166 Messina, Italy |
| Recommended Citation GB/T 7714 | Lin, Yangming,Sun, Xiaoyan,Su, Dang Sheng,et al. Catalysis by hybrid sp(2)/sp(3) nanodiamonds and their role in the design of advanced nanocarbon materials[J]. CHEMICAL SOCIETY REVIEWS,2018,47(22):8438-8473. |
| APA | Lin, Yangming,Sun, Xiaoyan,Su, Dang Sheng,Centi, Gabriele,&Perathoner, Siglinda.(2018).Catalysis by hybrid sp(2)/sp(3) nanodiamonds and their role in the design of advanced nanocarbon materials.CHEMICAL SOCIETY REVIEWS,47(22),8438-8473. |
| MLA | Lin, Yangming,et al."Catalysis by hybrid sp(2)/sp(3) nanodiamonds and their role in the design of advanced nanocarbon materials".CHEMICAL SOCIETY REVIEWS 47.22(2018):8438-8473. |
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