| Facet Sensitivity of Capping Ligand-Free Ag Crystals in CO2 Electrochemical Reduction to CO | |
| Yang, Min1; Zhang, Jiazhou2; Cao, Yongyong3; Wu, Minfang2; Qian, Kun1; Zhang, Zhenhua1; Liu, Hongyang4; Wang, Jianguo3; Chen, Wei2; Huang, Weixin1 | |
| 通讯作者 | Wang, Jianguo(jgw@zjut.edu.cn) ; Chen, Wei(chenw@sari.ac.cn) ; Huang, Weixin(huangwx@ustc.edu.cn) |
| 2018-11-22 | |
| 发表期刊 | CHEMCATCHEM
 |
| ISSN | 1867-3880 |
| 卷号 | 10期号:22页码:5128-5134 |
| 摘要 | Silver-based electrocatalysts are active in catalyzing electrochemical reduction of CO2 to CO. We herein report synthesis of capping ligand-free Ag cubes and octahedra by morphology-preserved CO reduction from corresponding Ag2O counterparts and their performance in electrochemical reduction of CO2. Ag cubes are much more active than Ag octahedra and exhibit a stable CO formation rate as high as 142.4 mmol(CO) g(cat)(-1) h(-1) at -0.95 V (vs. RHE). Ag films transiently formed on Ag2O crystals during CO2 electroreduction were observed more active than Ag crystals, revealing a promoting effect of Ag2O substrate on electrocatalytic activity of Ag film. These results clearly identify a facet sensitivity of silver electrocatalysts and highlight the importance of surface cleanness of Ag colloids as efficient electrocatalysts. |
| 关键词 | Ligand-free Ag crystals facet sensitivity CO2 electrochemical reduction Ag film DFT |
| 资助者 | National Key R&D Program of MOST ; National Natural Science Foundation of China ; MOE Changjiang Scholars Program ; MOE Fundamental Research Funds for the Central Universities ; Collaborative Innovation Center of Suzhou Nano Science and Technology |
| DOI | 10.1002/cctc.201801423 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 资助项目 | National Key R&D Program of MOST[2017YFB0602205] ; National Natural Science Foundation of China[21525313] ; MOE Changjiang Scholars Program ; MOE Fundamental Research Funds for the Central Universities[WK2060030017] ; Collaborative Innovation Center of Suzhou Nano Science and Technology |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| WOS记录号 | WOS:000451444000006 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.imr.ac.cn/handle/321006/130579 |
| 专题 | 中国科学院金属研究所 |
| 通讯作者 | Wang, Jianguo; Chen, Wei; Huang, Weixin |
| 作者单位 | 1.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Mat Energy Convers, Dept Chem Phys, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Shanghai Adv Res Inst, CAS Key Lab Low Carbon Convers Sci & Engn, Shanghai 201210, Peoples R China 3.Zhejiang Univ Technol, Coll Chem Engn, Ind Catalysis Inst, Hangzhou 310032, Zhejiang, Peoples R China 4.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Min,Zhang, Jiazhou,Cao, Yongyong,et al. Facet Sensitivity of Capping Ligand-Free Ag Crystals in CO2 Electrochemical Reduction to CO[J]. CHEMCATCHEM,2018,10(22):5128-5134. |
| APA | Yang, Min.,Zhang, Jiazhou.,Cao, Yongyong.,Wu, Minfang.,Qian, Kun.,...&Huang, Weixin.(2018).Facet Sensitivity of Capping Ligand-Free Ag Crystals in CO2 Electrochemical Reduction to CO.CHEMCATCHEM,10(22),5128-5134. |
| MLA | Yang, Min,et al."Facet Sensitivity of Capping Ligand-Free Ag Crystals in CO2 Electrochemical Reduction to CO".CHEMCATCHEM 10.22(2018):5128-5134. |
| 条目包含的文件 | 条目无相关文件。 | |||||
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