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Initial corrosion behavior of pure zinc in simulated tropical marine atmosphere
Yin, Qi1,2; Wang, Zhen-yao1; Pan, Chen1
通讯作者Wang, Zhen-yao(zhywang@imr.ac.cn)
2018-12-01
发表期刊TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
ISSN1003-6326
卷号28期号:12页码:2582-2591
摘要The initial corrosion behavior of pure zinc in a simulated tropical marine atmosphere was investigated using gravimetric method, scanning electron microscope combined with energy dispersive spectroscopy (SEM-EDS), X-ray diffractometry (XRD), Fourier transform infrared spectrometry (FTIR) and electrochemical impedance spectroscopy (EIS). The kinetics of corrosion process is a decelerating process following the empirical equation D=At-n (n<1). The protectiveness of the corrosion product layer could be attributed to the formation of simonkolleite, Zn-5(OH)(8)Cl-2 center dot H2O, which could inhibit the rate determining step, namely charge transfer step, of the electrochemical corrosion process. A model of the evolution process of the product layers formed on zinc was proposed. In addition, the regularity of the corrosion rate of zinc as a function of the NaCl deposition rate can be described by a power function.
关键词zinc corrosion kinetics corrosion product electrochemical impedance spectroscopy (EIS) simonkolleite
资助者Guangzhou Industry-University-Research Collaborative Innovation Alliance Special Program, China ; National Natural Science Foundation of China
DOI10.1016/S1003-6326(18)64905-2
收录类别SCI
语种英语
资助项目Guangzhou Industry-University-Research Collaborative Innovation Alliance Special Program, China[201604046014] ; National Natural Science Foundation of China[51671197] ; National Natural Science Foundation of China[51601199]
WOS研究方向Metallurgy & Metallurgical Engineering
WOS类目Metallurgy & Metallurgical Engineering
WOS记录号WOS:000454537400021
出版者ELSEVIER SCIENCE BV
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/130990
专题中国科学院金属研究所
通讯作者Wang, Zhen-yao
作者单位1.Chinese Acad Sci, Environm Corros Ctr, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China
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Yin, Qi,Wang, Zhen-yao,Pan, Chen. Initial corrosion behavior of pure zinc in simulated tropical marine atmosphere[J]. TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,2018,28(12):2582-2591.
APA Yin, Qi,Wang, Zhen-yao,&Pan, Chen.(2018).Initial corrosion behavior of pure zinc in simulated tropical marine atmosphere.TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,28(12),2582-2591.
MLA Yin, Qi,et al."Initial corrosion behavior of pure zinc in simulated tropical marine atmosphere".TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA 28.12(2018):2582-2591.
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