| Palladium nanoclusters immobilized on defective nanodiamond-graphene core-shell supports for semihydrogenation of phenylacetylene | |
| Huang, Fei1,2; Jia, Zhimin1,2; Diao, Jiangyong1; Yuan, Hua3; Su, Dangsheng1; Liu, Hongyang1 | |
| Corresponding Author | Liu, Hongyang(liuhy@imr.ac.cn) |
| 2019-06-01 | |
| Source Publication | JOURNAL OF ENERGY CHEMISTRY
 |
| ISSN | 2095-4956 |
| Volume | 33Pages:31-36 |
| Abstract | We report a nanocarbon material with nanodiamond (ND) core and graphene shell (ND@G) as a support for Pd nanocatalysts. The designed catalyst performed good selectivity of styrene (85.2%) at full conversion of phenylacetylene and superior stability under mild conditions. Supported Pd catalysts are characterized by means of high resolution transmission electron microscopy (HRTEM), Raman, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and H-2 temperature-programmed reduction (H-2-TPR). The results clearly show that formation of the strong metal-support interaction (SMSI) between Pd nanoclusters and the defective graphene shell helpfully modifies the selectivity and stability of the Pd-based catalysts. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved. |
| Keyword | Selective hydrogenation Palladium nanoclusters Nanocarbon support Liquid-phase hydrogenation |
| Funding Organization | Ministry of Science and Technology ; National Natural Science Foundation of China ; Youth Innovation Promotion Association (CAS) ; Sinopec China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Chongqing Research Program of Basic Research and Frontier Technology ; Scientific and Technological Research Program of Chongqing Municipal Education Commission |
| DOI | 10.1016/j.jechem.2018.08.006 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Ministry of Science and Technology[2016YFA0204100] ; National Natural Science Foundation of China[21573254] ; National Natural Science Foundation of China[21703261] ; National Natural Science Foundation of China[91545110] ; Youth Innovation Promotion Association (CAS) ; Sinopec China[XDA09030103] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA09030103] ; Chongqing Research Program of Basic Research and Frontier Technology[cstc2016jcyjA0432] ; Scientific and Technological Research Program of Chongqing Municipal Education Commission[KJ1600328] |
| WOS Research Area | Chemistry ; Energy & Fuels ; Engineering |
| WOS Subject | Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:000457881000005 |
| Publisher | ELSEVIER SCIENCE BV |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/131522 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Liu, Hongyang |
| Affiliation | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China 3.Chongqing Normal Univ, Coll Chem, Chongqing 401331, Peoples R China |
| Recommended Citation GB/T 7714 | Huang, Fei,Jia, Zhimin,Diao, Jiangyong,et al. Palladium nanoclusters immobilized on defective nanodiamond-graphene core-shell supports for semihydrogenation of phenylacetylene[J]. JOURNAL OF ENERGY CHEMISTRY,2019,33:31-36. |
| APA | Huang, Fei,Jia, Zhimin,Diao, Jiangyong,Yuan, Hua,Su, Dangsheng,&Liu, Hongyang.(2019).Palladium nanoclusters immobilized on defective nanodiamond-graphene core-shell supports for semihydrogenation of phenylacetylene.JOURNAL OF ENERGY CHEMISTRY,33,31-36. |
| MLA | Huang, Fei,et al."Palladium nanoclusters immobilized on defective nanodiamond-graphene core-shell supports for semihydrogenation of phenylacetylene".JOURNAL OF ENERGY CHEMISTRY 33(2019):31-36. |
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