| Fabrication of nanometer-sized high-silica SAPO-5 and its enhanced photocatalytic performance for methyl orange degradation | |
| Qiu, Lingfang1; Zhou, Zhiwei1; Yu, Yaqian1; Zhang, Hao1; Qian, Yuhai2; Yang, Yuyu1; Duo, Shuwang1,2 | |
| Corresponding Author | Duo, Shuwang(swduo@imr.ac.cn) |
| 2019-03-01 | |
| Source Publication | RESEARCH ON CHEMICAL INTERMEDIATES
 |
| ISSN | 0922-6168 |
| Volume | 45Issue:3Pages:1457-1473 |
| Abstract | Higher efficient degradation of methyl orange (MO) was demonstrated with nanometer-sized high-silica SAPO-5. By a hydrothermal process, synthesized high-silica SAPO-5 and low-silica SAPO-5 showed Si-to-Al ratios of 4.20 and 0.11, respectively. High-silica SAPO-5 showed much better MO degradation efficiency with a dosage of 70mg in MO solution with a concentration of 10mg/L under ultraviolet illumination. High-silica SAPO-5 also exhibited good producibility for preparation and stable photocatalytic activity even after the fifth recycling test. Optical characterizations of DRS, XPS, photocurrent density and time-resolved fluorescence were carried out for SAPO-5 samples. Finally, free radical and hole scavenging experiments were investigated for high-silica SAPO-5, and a MO photodegradation mechanism based on the charge transfer excited state of [Al2+-O-]* was proposed. This work highlights great prospects of high-silica SAPO-5 for organic pollutant removal with virtues of ideal efficiency and environmental friendliness. |
| Keyword | SAPO-5 High-silica Nanometer-sized Photocatalysis |
| Funding Organization | National Natural Science Foundation of China ; Natural Science Foundation of Jiangxi Province ; Doctoral Scientific Research Starting Foundation of Jiangxi Science and Technology Normal University ; Project of Sci-Tech Innovative Team for Nano Functional Materials of Jiangxi Science and Technology Normal University |
| DOI | 10.1007/s11164-018-3675-7 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51363007] ; Natural Science Foundation of Jiangxi Province[20171BAB206008] ; Doctoral Scientific Research Starting Foundation of Jiangxi Science and Technology Normal University[2017BSQD003] ; Project of Sci-Tech Innovative Team for Nano Functional Materials of Jiangxi Science and Technology Normal University[YC 2017-X17] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000459004900035 |
| Publisher | SPRINGER |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/131891 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Duo, Shuwang |
| Affiliation | 1.Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Surface Engn, Nanchang 330013, Jiangxi, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China |
| Recommended Citation GB/T 7714 | Qiu, Lingfang,Zhou, Zhiwei,Yu, Yaqian,et al. Fabrication of nanometer-sized high-silica SAPO-5 and its enhanced photocatalytic performance for methyl orange degradation[J]. RESEARCH ON CHEMICAL INTERMEDIATES,2019,45(3):1457-1473. |
| APA | Qiu, Lingfang.,Zhou, Zhiwei.,Yu, Yaqian.,Zhang, Hao.,Qian, Yuhai.,...&Duo, Shuwang.(2019).Fabrication of nanometer-sized high-silica SAPO-5 and its enhanced photocatalytic performance for methyl orange degradation.RESEARCH ON CHEMICAL INTERMEDIATES,45(3),1457-1473. |
| MLA | Qiu, Lingfang,et al."Fabrication of nanometer-sized high-silica SAPO-5 and its enhanced photocatalytic performance for methyl orange degradation".RESEARCH ON CHEMICAL INTERMEDIATES 45.3(2019):1457-1473. |
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