| In-situ synthesis of porous Ni2P nanosheets for efficient and stable hydrogen evolution reaction | |
| Jin, Xin1,2; Li, Jing2; Cui, Yuting1; Liu, Xiaoyuan2; Wang, Ke2; Zhou, Yang2; Yang, Wenjin2; Zhang, Xinglai2; Zhang, Cai2; Jiang, Xin2; Liu, Baodan2 | |
| Corresponding Author | Cui, Yuting(cytcyt111@163.com) ; Liu, Baodan(baodanliu@hotmail.com) |
| 2019-03-01 | |
| Source Publication | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
 |
| ISSN | 0360-3199 |
| Volume | 44Issue:12Pages:5739-5747 |
| Abstract | The design and development of highly efficient and stable non-noble metal electrocatalysts for hydrogen evolution reaction (HER) have attracted increasing attention. However, some key issues related to large overpotential, high cost and poor stability at high current density still remains challenging. In this work, we report a facile in-situ integration strategy of porous Ni2P nanosheet catalysts on 3D Ni foam framework (P-Ni2P/NF) for efficient and stable HER in alkaline medium. The two-step method can creates high density of ultra-thin porous Ni2P nanosheets firmly rooted into Ni foam substrate which can guarantee excellent electrical contacts, strong substrate adherence and large amount of active sites. Such a binder-free flexible HER cathode exhibits superior electrocatalytic performance with an overpotential of 134 mV at current density of 10 mA cm(-2). It also shows superior stability at higher current densities of 100 and 500 mA cm(-2) for at least 48 h and negligible performance degradation is observed. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. |
| Keyword | Nickel phosphide In-situ synthesis Porous nanosheets Hydrogen evolution reaction Electrocatalysis |
| Funding Organization | National Natural Science Foundation of China ; Open Fund of the State Key Laboratory of Optoelectronic Materials and Technologies (Sun Yat-Sen University) ; Basic Science Innovation Program of Shenyang National Laboratory for Materials Science ; Program for Leading Talents in Science and Technology Innovation of Chongqing City |
| DOI | 10.1016/j.ijhydene.2019.01.042 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51702326] ; National Natural Science Foundation of China[51872296] ; Open Fund of the State Key Laboratory of Optoelectronic Materials and Technologies (Sun Yat-Sen University)[OEMT-2017-KF-02] ; Basic Science Innovation Program of Shenyang National Laboratory for Materials Science[2017RP25] ; Program for Leading Talents in Science and Technology Innovation of Chongqing City[cstc2014kjcxljrc0023] |
| WOS Research Area | Chemistry ; Electrochemistry ; Energy & Fuels |
| WOS Subject | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
| WOS ID | WOS:000461410200008 |
| Publisher | PERGAMON-ELSEVIER SCIENCE LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/132021 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Cui, Yuting; Liu, Baodan |
| Affiliation | 1.Chongqing Normal Univ, Coll Phys & Elect Engn, Chongqing 400047, Peoples R China 2.Chinese Acad Sci, IMR, Shenyang Natl Lab Mat Sci SYNL, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China |
| Recommended Citation GB/T 7714 | Jin, Xin,Li, Jing,Cui, Yuting,et al. In-situ synthesis of porous Ni2P nanosheets for efficient and stable hydrogen evolution reaction[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2019,44(12):5739-5747. |
| APA | Jin, Xin.,Li, Jing.,Cui, Yuting.,Liu, Xiaoyuan.,Wang, Ke.,...&Liu, Baodan.(2019).In-situ synthesis of porous Ni2P nanosheets for efficient and stable hydrogen evolution reaction.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,44(12),5739-5747. |
| MLA | Jin, Xin,et al."In-situ synthesis of porous Ni2P nanosheets for efficient and stable hydrogen evolution reaction".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 44.12(2019):5739-5747. |
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