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Chemical decomposition along dislocations during plastic deformation
Yang, Zhiqing; Hu, Weiwei; Zhang, Lifeng; Ye, Hengqiang
通讯作者Yang, Zhiqing(yangzq@imr.ac.cn)
2019-03-11
发表期刊PHYSICAL REVIEW MATERIALS
ISSN2475-9953
卷号3期号:3页码:6
摘要Chemical decomposition of compound phases has been observed in many engineering alloys subjected to plastic deformation. However, little is known about the role of dislocations moving within compounds in their deformation-induced chemical decomposition. We report observations of chemical decomposition of compound crystals along dislocations with atomic resolution, which is inconsistent with the well-established dislocation theory. Transition-metal (TM) and rare-earth element (RE) atoms in the wake of moving partial dislocations are removed out of Mg-TM-RE compounds in magnesium alloys, producing magnesium nanoslices inside. Glide of partial dislocations forces local transformation from face-centered cubic to hexagonal structures with supersaturated TM and RE in Mg-TM-RE compounds. TM and RE atoms behind moving partial dislocations are then relocated into adjacent magnesium grains through pipe diffusion, under the driving force of supersaturated chemical potential. Our observations demonstrate atomically spatial coupling of individual moving dislocations and chemical decomposition within bulk crystals during plastic deformation, providing insights into dislocations and their roles in materials.
资助者National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS
DOI10.1103/PhysRevMaterials.3.033602
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[51390473] ; National Natural Science Foundation of China[51371178] ; National Natural Science Foundation of China[51771202] ; Key Research Program of Frontier Sciences, CAS[QYZDY-SSW-JSC027]
WOS研究方向Materials Science
WOS类目Materials Science, Multidisciplinary
WOS记录号WOS:000461076800001
出版者AMER PHYSICAL SOC
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/132242
专题中国科学院金属研究所
通讯作者Yang, Zhiqing
作者单位Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
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Yang, Zhiqing,Hu, Weiwei,Zhang, Lifeng,et al. Chemical decomposition along dislocations during plastic deformation[J]. PHYSICAL REVIEW MATERIALS,2019,3(3):6.
APA Yang, Zhiqing,Hu, Weiwei,Zhang, Lifeng,&Ye, Hengqiang.(2019).Chemical decomposition along dislocations during plastic deformation.PHYSICAL REVIEW MATERIALS,3(3),6.
MLA Yang, Zhiqing,et al."Chemical decomposition along dislocations during plastic deformation".PHYSICAL REVIEW MATERIALS 3.3(2019):6.
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