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Phase evolution of reactive sputtering synthesized holmium silicate coatings
Hu, Wanpeng1,2; Zhang, Jie1; Nian, Hongqiang3; Wang, Jingyang1
通讯作者Zhang, Jie(jiezhang@imr.ac.cn)
2019
发表期刊JOURNAL OF THE AMERICAN CERAMIC SOCIETY
ISSN0002-7820
卷号102期号:1页码:490-497
摘要Holmium silicates are promising environmental barrier coatings (EBCs) materials for Si-based non-oxide ceramics due to their excellent thermal and mechanical properties. In the present work, the phase evolution of holmium silicate coatings synthesized by reactive sputtering was systematically studied. The monosilicate crystallized in an X1-Ho2SiO5 phase at 1000 degrees C and transformed to an X2-Ho2SiO5 phase at 1200 degrees C. The phase transition is not problematic for the coating process because the X1- and X-2-Ho2SiO5 phases have similar coefficients of thermal expansion (CTEs). For the holmium disilicates, the stoichiometry obviously influenced polymorphic phase evolutions. Relatively Ho2O3-rich compounds promoted the formation of gamma-Ho2Si2O7 phase at lower temperatures. This study on phase evolution vs temperature and stoichiometry can provide a guideline to optimize the processing and the properties of advanced holmium silicate EBCs.
关键词environmental barrier coatings holmium silicates phase evolution stoichiometry
资助者National Natural Science Foundation of China ; National Key R&D Program of China
DOI10.1111/jace.15930
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[51402311] ; National Natural Science Foundation of China[51772302] ; National Key R&D Program of China[2017YFB0703201]
WOS研究方向Materials Science
WOS类目Materials Science, Ceramics
WOS记录号WOS:000459932500051
出版者WILEY
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/132325
专题中国科学院金属研究所
通讯作者Zhang, Jie
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang, Liaoning, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai, Peoples R China
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GB/T 7714
Hu, Wanpeng,Zhang, Jie,Nian, Hongqiang,et al. Phase evolution of reactive sputtering synthesized holmium silicate coatings[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY,2019,102(1):490-497.
APA Hu, Wanpeng,Zhang, Jie,Nian, Hongqiang,&Wang, Jingyang.(2019).Phase evolution of reactive sputtering synthesized holmium silicate coatings.JOURNAL OF THE AMERICAN CERAMIC SOCIETY,102(1),490-497.
MLA Hu, Wanpeng,et al."Phase evolution of reactive sputtering synthesized holmium silicate coatings".JOURNAL OF THE AMERICAN CERAMIC SOCIETY 102.1(2019):490-497.
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