| On the effect of mesoporosity of FAU Y zeolites in the liquid-phase catalysis | |
| Zhang, Rongxin1; Xu, Shaojun1; Raja, Duaa1; Khusni, Nor Binti1; Liu, Jinmin2; Zhang, Jiaoyu3; Abdulridha, Samer1; Xiang, Huan1; Jiang, Songshan1,4; Guan, Yanan2; Jiao, Yilai1,2; Fan, Xiaolei1 | |
| Corresponding Author | Jiao, Yilai(yljiao@imr.ac.cn) ; Fan, Xiaolei(xiaolei.fan@manchester.ac.uk) |
| 2019-04-01 | |
| Source Publication | MICROPOROUS AND MESOPOROUS MATERIALS
 |
| ISSN | 1387-1811 |
| Volume | 278Pages:297-306 |
| Abstract | The porosity and acidity of three commercial FAU Y zeolites (including the original HY-2.6 and dealuminated HY-15/-30 zeolites) were studied comprehensively using nitrogen (N-2) physisorption, and mercury (Hg) porosimetry, ammonia temperature-programmed desorption (NH3-TPD) and pyridine Fourier transform infrared (pyridine-IR) analyses. The combined N-2 physisorption and Hg porosimetry is a useful tool to evaluate the hierarchical mesoporosity in the dealuminated samples, revealing that HY-15 and HY-30 possess > 50% open mesoporosity in the mesopores range of 5-10 nm. The acidity of the dealuminated Y zeolites has been reduced significantly in comparison to that of the original HY-2.6, e.g. Bronsted acidity decreased by ca. 69 folds by dealuminating HY-2.6 to HY-30. Catalytic results of Fischer esterification of methanol with carboxylic acids and aldol condensation of benzaldehyde with 1-heptanal have evidenced that the critical role of mesoporosity of the dealuminated Y zeolites in liquid-phase reactions. For example, in the esterification of lauric acid with methanol, HY-15 and HY-30 with hierarchical mesopores showed better catalytic activity (Le. conversion of lauric acid: 7.9% and 24.5%, respectively) than HY-2.6 (4.0%). The analysis of the catalytic results along with the acidic property suggests that the acidity is less influential than the porosity of zeolite catalysts. Results from this study allow us to explain the origin of the high activity of zeolites with mesoporosity in the liquid-phase catalysis. |
| Keyword | Zeolite Y Mesoporosity Acidity Aldol condensation Fischer esterification |
| Funding Organization | Engineering and Physical Sciences Research Council ; Liaoning Provincial Natural Science Foundation of China ; China Scholarship Council ; University of Manchester President's Doctoral Scholar Award ; CSC scholarship ; UK China Joint Research and Innovation Partnership Fund (UK as the Newton Fund PhD Placement Grant) by the CSC ; British Council |
| DOI | 10.1016/j.micromeso.2018.12.003 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Engineering and Physical Sciences Research Council[EP/R000670/1] ; Liaoning Provincial Natural Science Foundation of China[20180510012] ; China Scholarship Council[201604910181] ; University of Manchester President's Doctoral Scholar Award ; CSC scholarship[201606150068] ; UK China Joint Research and Innovation Partnership Fund (UK as the Newton Fund PhD Placement Grant) by the CSC[201603780091] ; British Council |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| WOS Subject | Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| WOS ID | WOS:000459841900036 |
| Publisher | ELSEVIER SCIENCE BV |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/132341 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Jiao, Yilai; Fan, Xiaolei |
| Affiliation | 1.Univ Manchester, Sch Chem Engn & Analyt Sci, Oxford Rd, Manchester M13 9PL, Lancs, England 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China 3.China Univ Petr East China, State Key Lab Heavy Oil Proc, Qingdao 266555, Peoples R China 4.South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang, Rongxin,Xu, Shaojun,Raja, Duaa,et al. On the effect of mesoporosity of FAU Y zeolites in the liquid-phase catalysis[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2019,278:297-306. |
| APA | Zhang, Rongxin.,Xu, Shaojun.,Raja, Duaa.,Khusni, Nor Binti.,Liu, Jinmin.,...&Fan, Xiaolei.(2019).On the effect of mesoporosity of FAU Y zeolites in the liquid-phase catalysis.MICROPOROUS AND MESOPOROUS MATERIALS,278,297-306. |
| MLA | Zhang, Rongxin,et al."On the effect of mesoporosity of FAU Y zeolites in the liquid-phase catalysis".MICROPOROUS AND MESOPOROUS MATERIALS 278(2019):297-306. |
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