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2D titanium carbide (MXene) electrodes with lower-F surface for high performance lithium-ion batteries
Lu, Ming1,2; Li, Haojie2,3; Han, Wenjuan2,4; Chen, Junnan2; Shi, Wen2; Wang, Jiaheng3; Meng, Xiang-Min5; Qi, Jingang6; Li, Haibo4; Zhang, Bingsen2; Zhang, Wei1; Zheng, Weitao1
通讯作者Zhang, Bingsen(bszhang@imr.ac.cn) ; Zhang, Wei(weizhang@jlu.edu.cn) ; Zheng, Weitao(wtzheng@jlu.edu.cn)
2019-04-01
发表期刊JOURNAL OF ENERGY CHEMISTRY
ISSN2095-4956
卷号31页码:148-153
摘要MXene has shown distinctive advantages as anode materials of lithium-ion batteries. However, local surface chemistry, which was confirmed that can block ion transfer and limit redox reaction, has a significant effect on electrochemical performance. Herein, annealing MXene under hydrogen was employed for removing -F and turning -OH to -O terminations. We demonstrate that it improves the kinetics of Li-ion transport between the electrolyte and electrode. As a result, a lower interfacial charge transfer impedance was obtained. The electrochemical measurement exhibited that a nearly 2-fold increase of specific capacity was achieved for the annealed MXene. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
关键词Ti3C2 MXene Li-ion Hydrogen -F content
资助者National Key R&D Program of China ; Jilin Province/Jilin University co-Construction Project-Funds for New Materials ; National Natural Science Foundation of China ; Youth Innovation Promotion Association CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences Chinese Academy of Sciences ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Double-First Class Discipline for Materials Science Engineering
DOI10.1016/j.jechem.2018.05.017
收录类别SCI
语种英语
资助项目National Key R&D Program of China[2016YFA0200400] ; Jilin Province/Jilin University co-Construction Project-Funds for New Materials[SXGJSF2017-3] ; Jilin Province/Jilin University co-Construction Project-Funds for New Materials[Branch-2/440050316A36] ; National Natural Science Foundation of China[91545119] ; National Natural Science Foundation of China[21761132025] ; National Natural Science Foundation of China[21773269] ; National Natural Science Foundation of China[51372095] ; Youth Innovation Promotion Association CAS[2015152] ; Strategic Priority Research Program of the Chinese Academy of Sciences Chinese Academy of Sciences[XDA09030103] ; Strategic Priority Research Program of the Chinese Academy of Sciences Chinese Academy of Sciences[XDA09040203] ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Double-First Class Discipline for Materials Science Engineering
WOS研究方向Chemistry ; Energy & Fuels ; Engineering
WOS类目Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS记录号WOS:000460174000018
出版者ELSEVIER SCIENCE BV
引用统计
被引频次:122[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/132349
专题中国科学院金属研究所
通讯作者Zhang, Bingsen; Zhang, Wei; Zheng, Weitao
作者单位1.Jilin Univ, Electron Microscopy Ctr, Int Ctr Future Sci, Sch Mat Sci & Engn,Key Lab Automobile Mat MOE, Changchun 130012, Jilin, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
3.Hefei Univ Technol, Dept Mech Engn, Xuancheng 242000, Anhui, Peoples R China
4.Jilin Normal Univ, Minist Educ, Key Lab Funct Mat Phys & Chem, Siping 136000, Jilin, Peoples R China
5.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China
6.Liaoning Univ Technol, Sch Mat Sci & Engn, Jinzhou 121001, Liaoning, Peoples R China
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Lu, Ming,Li, Haojie,Han, Wenjuan,et al. 2D titanium carbide (MXene) electrodes with lower-F surface for high performance lithium-ion batteries[J]. JOURNAL OF ENERGY CHEMISTRY,2019,31:148-153.
APA Lu, Ming.,Li, Haojie.,Han, Wenjuan.,Chen, Junnan.,Shi, Wen.,...&Zheng, Weitao.(2019).2D titanium carbide (MXene) electrodes with lower-F surface for high performance lithium-ion batteries.JOURNAL OF ENERGY CHEMISTRY,31,148-153.
MLA Lu, Ming,et al."2D titanium carbide (MXene) electrodes with lower-F surface for high performance lithium-ion batteries".JOURNAL OF ENERGY CHEMISTRY 31(2019):148-153.
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