Improved dispersion of the graphene and corrosion resistance of waterborne epoxy-graphene composites by minor cellulose nanowhiskers | |
Nie, Jing1,2; Liu, Dongyan1,2; Li, Songtao1,2; Qiu, Zhangweijia1,2; Ma, Na1,2; Sui, Guoxin1,2 | |
通讯作者 | Liu, Dongyan(dyliu@imr.ac.cn) ; Sui, Guoxin(gxsui@imr.ac.cn) |
2019-06-20 | |
发表期刊 | JOURNAL OF APPLIED POLYMER SCIENCE
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ISSN | 0021-8995 |
卷号 | 136期号:24页码:9 |
摘要 | The uniform dispersion of graphene (GN) in a polymer matrix is still challenging at high loadings. In this study, we introduced a tiny number of cellulose nanowhiskers (CNWs; CNWs/GN = 1:20 w/w) to improve the dispersion of GN nanoplatelets in a waterborne epoxy (WEP) matrix at a GN loading of 1.0 wt %. Compared with that of 1.0% GN-WEP, the Young's modulus of the 1.0% GN-WEP-CNWs was enhanced by about 20.5%. The glass-transition temperature increased from 70.4 degrees C for 1.0% GN-WEP to 72.8 degrees C for 1.0% GN-WEP-CNWs. The water contact angle of composite film increased by 17 degrees, from about 79 degrees for the film without CNWs to about 96 degrees for the film with CNWs. The anticorrosion efficiency of the coatings was also evaluated with the potentiodynamic polarization and electrochemical impedance spectroscopy techniques. The results reveal the CNW-containing coating showed better corrosion resistance for mild steel and could be applied as a green dispersant for GN in WEP coatings. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47631. |
关键词 | cellulose and other wood products coatings electrochemistry nanotubes graphene and fullerenes resins |
DOI | 10.1002/app.47631 |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Polymer Science |
WOS类目 | Polymer Science |
WOS记录号 | WOS:000461893300012 |
出版者 | WILEY |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/132547 |
专题 | 中国科学院金属研究所 |
通讯作者 | Liu, Dongyan; Sui, Guoxin |
作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230000, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Nie, Jing,Liu, Dongyan,Li, Songtao,et al. Improved dispersion of the graphene and corrosion resistance of waterborne epoxy-graphene composites by minor cellulose nanowhiskers[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2019,136(24):9. |
APA | Nie, Jing,Liu, Dongyan,Li, Songtao,Qiu, Zhangweijia,Ma, Na,&Sui, Guoxin.(2019).Improved dispersion of the graphene and corrosion resistance of waterborne epoxy-graphene composites by minor cellulose nanowhiskers.JOURNAL OF APPLIED POLYMER SCIENCE,136(24),9. |
MLA | Nie, Jing,et al."Improved dispersion of the graphene and corrosion resistance of waterborne epoxy-graphene composites by minor cellulose nanowhiskers".JOURNAL OF APPLIED POLYMER SCIENCE 136.24(2019):9. |
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