| Direct Conversion of Acetylene and 1,2-Dichloroethane to Vinyl Chloride Monomer over a Supported Carbon Nitride Catalyst: Tunable Activity Controlled by the Synthesis Temperature | |
| Sun, Xi1; Liu, Xi4; Qin, Yucai2; Qiang, Li2; He, Yu-Peng2; Su, Dangsheng3; Song, Lijuan2; Sun, Zhaolin1 | |
| Corresponding Author | Su, Dangsheng(dssu@dicp.ac.cn) ; Song, Lijuan(lsong56@263.net) ; Sun, Zhaolin(zlsun56@263.net) |
| 2019-04-10 | |
| Source Publication | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| ISSN | 0888-5885 |
| Volume | 58Issue:14Pages:5404-5413 |
| Abstract | A carbon supported carbon nitride is reported here as a catalyst for the direct conversion of acetylene and 1,2-dichloroethane (EDC) to vinyl chloride monomer (VCM). We demonstrate that increasing the synthesis temperature of the carbon nitride material leads to a catalyst with higher catalytic activity toward VCM production. The catalysts were characterized by acetylene temperature-programmed desorption, X-ray photoelectron spectroscopy, high-resolution TEM, electron energy loss spectroscopy, and computational methods, showing that the improved activity for the catalysts can be ascribed to both the higher proportion of pyridinic N and the more positive lowest unoccupied molecular orbital of the catalyst, resulting from the increased degree of polymerization of carbon nitride. These findings highlight the role of polymerization conditions in increasing the catalytic activity of carbon nitride catalysts and provide a strategy for the selective synthesis of highly active carbon nitride catalysts for the one-step synthesis of VCM from acetylene and EDC. |
| Funding Organization | National Science Foundation of China ; Department of Science and Technology of Liaoning Province |
| DOI | 10.1021/acs.iecr.8b05942 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Science Foundation of China[21376114] ; National Science Foundation of China[U1662135] ; National Science Foundation of China[21673273] ; Department of Science and Technology of Liaoning Province[2013219006] |
| WOS Research Area | Engineering |
| WOS Subject | Engineering, Chemical |
| WOS ID | WOS:000464769200006 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/132919 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Su, Dangsheng; Song, Lijuan; Sun, Zhaolin |
| Affiliation | 1.Lanzhou Univ, Dept Chem, 222 South Tianshui Rd, Lanzhou 730000, Gansu, Peoples R China 2.Liaoning Shihua Univ, Key Lab Petrochem Catalyt Sci & Technol Liaoning, Fushun 113001, Liaoning, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 4.Synfuels China Technol Co Ltd, Syncat Beijing, Beijing 101407, Peoples R China |
| Recommended Citation GB/T 7714 | Sun, Xi,Liu, Xi,Qin, Yucai,et al. Direct Conversion of Acetylene and 1,2-Dichloroethane to Vinyl Chloride Monomer over a Supported Carbon Nitride Catalyst: Tunable Activity Controlled by the Synthesis Temperature[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2019,58(14):5404-5413. |
| APA | Sun, Xi.,Liu, Xi.,Qin, Yucai.,Qiang, Li.,He, Yu-Peng.,...&Sun, Zhaolin.(2019).Direct Conversion of Acetylene and 1,2-Dichloroethane to Vinyl Chloride Monomer over a Supported Carbon Nitride Catalyst: Tunable Activity Controlled by the Synthesis Temperature.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,58(14),5404-5413. |
| MLA | Sun, Xi,et al."Direct Conversion of Acetylene and 1,2-Dichloroethane to Vinyl Chloride Monomer over a Supported Carbon Nitride Catalyst: Tunable Activity Controlled by the Synthesis Temperature".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 58.14(2019):5404-5413. |
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