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Effect of graphitization of oxygen-modified carbon nanotubes in selective oxidation of acrolein
Zhong, Bingwei1; Huang, Rui2; Su, Dang Sheng2; Liu, Hongyang2
Corresponding AuthorZhong, Bingwei(20140040@zafu.edu.cn) ; Liu, Hongyang(Liuhy@imr.ac.cn)
2019-06-15
Source PublicationCATALYSIS TODAY
ISSN0920-5861
Volume330Pages:142-148
AbstractCNTs produced from chemical vapor deposition usually accompany with various impurities such as carbonaceous species and metal residues. In this work, the influence of graphitization and oxidation on the catalytic activity of the CNTs is investigated by using of acrolein oxidation reaction (ACR) as a probe reaction. The results suggest that the presence of amorphous carbon is detrimental to the catalytic performance because of the loss and reproducing from those of unstable functional groups on the surface. Kinetic measurements also reveal that the coverage of amorphous carbon attached on the carbon surface hampers the in-situ formation of active oxygen groups expoxy/lactone, reactant diffusion and ACR reaction. Our work provides valuable information on the design of modified carbon materials with more excellent properties and gives an alternative way for oxidation of aldehyde from an industrial point of view.
KeywordGraphitization Carbon nanotubes Selective oxidation Acrolein
Funding OrganizationZhejiang Provincial Natural Science Foundation of China ; Youth Innovation Promotion Association CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Research Foundation of Jiyang college of Zhejiang AF university ; College students' science and technology innovation project of shaoxing
DOI10.1016/j.cattod.2018.02.057
Indexed BySCI
Language英语
Funding ProjectZhejiang Provincial Natural Science Foundation of China[LQ16B030003] ; Youth Innovation Promotion Association CAS[2015152] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA09030103] ; Research Foundation of Jiyang college of Zhejiang AF university[JY2015RC003] ; Research Foundation of Jiyang college of Zhejiang AF university[JYYY1403] ; College students' science and technology innovation project of shaoxing[JYSXK1602]
WOS Research AreaChemistry ; Engineering
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS IDWOS:000463476300018
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/132991
Collection中国科学院金属研究所
Corresponding AuthorZhong, Bingwei; Liu, Hongyang
Affiliation1.Zhejiang A&F Univ, JiYang Coll, 77 Puyang Rd, Zhuji 311800, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Inst Shenyang Natl Lab Mat Sci, Catalyt Mat Div, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Zhong, Bingwei,Huang, Rui,Su, Dang Sheng,et al. Effect of graphitization of oxygen-modified carbon nanotubes in selective oxidation of acrolein[J]. CATALYSIS TODAY,2019,330:142-148.
APA Zhong, Bingwei,Huang, Rui,Su, Dang Sheng,&Liu, Hongyang.(2019).Effect of graphitization of oxygen-modified carbon nanotubes in selective oxidation of acrolein.CATALYSIS TODAY,330,142-148.
MLA Zhong, Bingwei,et al."Effect of graphitization of oxygen-modified carbon nanotubes in selective oxidation of acrolein".CATALYSIS TODAY 330(2019):142-148.
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