| Effect of graphitization of oxygen-modified carbon nanotubes in selective oxidation of acrolein | |
| Zhong, Bingwei1; Huang, Rui2; Su, Dang Sheng2; Liu, Hongyang2 | |
| Corresponding Author | Zhong, Bingwei(20140040@zafu.edu.cn) ; Liu, Hongyang(Liuhy@imr.ac.cn) |
| 2019-06-15 | |
| Source Publication | CATALYSIS TODAY
 |
| ISSN | 0920-5861 |
| Volume | 330Pages:142-148 |
| Abstract | CNTs produced from chemical vapor deposition usually accompany with various impurities such as carbonaceous species and metal residues. In this work, the influence of graphitization and oxidation on the catalytic activity of the CNTs is investigated by using of acrolein oxidation reaction (ACR) as a probe reaction. The results suggest that the presence of amorphous carbon is detrimental to the catalytic performance because of the loss and reproducing from those of unstable functional groups on the surface. Kinetic measurements also reveal that the coverage of amorphous carbon attached on the carbon surface hampers the in-situ formation of active oxygen groups expoxy/lactone, reactant diffusion and ACR reaction. Our work provides valuable information on the design of modified carbon materials with more excellent properties and gives an alternative way for oxidation of aldehyde from an industrial point of view. |
| Keyword | Graphitization Carbon nanotubes Selective oxidation Acrolein |
| Funding Organization | Zhejiang Provincial Natural Science Foundation of China ; Youth Innovation Promotion Association CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Research Foundation of Jiyang college of Zhejiang AF university ; College students' science and technology innovation project of shaoxing |
| DOI | 10.1016/j.cattod.2018.02.057 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Zhejiang Provincial Natural Science Foundation of China[LQ16B030003] ; Youth Innovation Promotion Association CAS[2015152] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA09030103] ; Research Foundation of Jiyang college of Zhejiang AF university[JY2015RC003] ; Research Foundation of Jiyang college of Zhejiang AF university[JYYY1403] ; College students' science and technology innovation project of shaoxing[JYSXK1602] |
| WOS Research Area | Chemistry ; Engineering |
| WOS Subject | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| WOS ID | WOS:000463476300018 |
| Publisher | ELSEVIER SCIENCE BV |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/132991 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Zhong, Bingwei; Liu, Hongyang |
| Affiliation | 1.Zhejiang A&F Univ, JiYang Coll, 77 Puyang Rd, Zhuji 311800, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Inst Shenyang Natl Lab Mat Sci, Catalyt Mat Div, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China |
| Recommended Citation GB/T 7714 | Zhong, Bingwei,Huang, Rui,Su, Dang Sheng,et al. Effect of graphitization of oxygen-modified carbon nanotubes in selective oxidation of acrolein[J]. CATALYSIS TODAY,2019,330:142-148. |
| APA | Zhong, Bingwei,Huang, Rui,Su, Dang Sheng,&Liu, Hongyang.(2019).Effect of graphitization of oxygen-modified carbon nanotubes in selective oxidation of acrolein.CATALYSIS TODAY,330,142-148. |
| MLA | Zhong, Bingwei,et al."Effect of graphitization of oxygen-modified carbon nanotubes in selective oxidation of acrolein".CATALYSIS TODAY 330(2019):142-148. |
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