The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring

doi:10.1038/s41467-019-09596-x

IMR OpenIR

	The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring
	Zhang, Zhiqi 1,2; Chen, Yugang 1,2; Zhou, Liqi 3,4; Chen, Chi 5; Han, Zhen 3,4; Zhang, Bingsen 6; Wu, Qiang 1,2; Yang, Lijun 1,2; Du, Lingyu 1,2; Bu, Yongfeng 1,2; Wang, Peng 3,4,7; Wang, Xizhang 1,2; Yang, Hui 5; Hu, Zheng 1,2
通讯作者	Wu, Qiang(wqchem@nju.edu.cn) ; Wang, Peng(wangpeng@nju.edu.cn) ; Hu, Zheng(zhenghu@nju.edu.cn)
	2019-04-10
发表期刊	NATURE COMMUNICATIONS
ISSN	2041-1723
卷号	10 页码:7
摘要	Single-site catalysts feature high catalytic activity but their facile construction and durable utilization are highly challenging. Herein, we report a simple impregnation-adsorption method to construct platinum single-site catalysts by synergic micropore trapping and nitrogen anchoring on hierarchical nitrogen-doped carbon nanocages. The optimal catalyst exhibits a record-high electrocatalytic hydrogen evolution performance with low overpotential, high mass activity and long stability, much superior to the platinum-based catalysts to date. Theoretical simulations and experiments reveal that the micropores with edge-nitrogendopants favor the formation of isolated platinum atoms by the micropore trapping and nitrogen anchoring of [PtCI6](2-), followed by the spontaneous dechlorination. The platinum-nitrogen bonds are more stable than the platinum-carbon ones in the presence of adsorbed hydrogen atoms, leading to the superior hydrogen evolution stability of platinum single-atoms on nitrogen-doped carbon. This method has been successfully applied to construct the single-site catalysts of other precious metals such as palladium, gold and iridium.
资助者	National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Basic Research Program of China
DOI	10.1038/s41467-019-09596-x
收录类别	SCI
语种	英语
资助项目	National Key Research and Development Program of China[2017YFA0206500] ; National Key Research and Development Program of China[2018YFA0209103] ; National Natural Science Foundation of China[21832003] ; National Natural Science Foundation of China[21773111] ; National Natural Science Foundation of China[51571110] ; National Natural Science Foundation of China[21573107] ; National Natural Science Foundation of China[11474147] ; National Natural Science Foundation of China[11874199] ; National Basic Research Program of China[2015CB654901]
WOS研究方向	Science & Technology - Other Topics
WOS类目	Multidisciplinary Sciences
WOS记录号	WOS:000463984400006
出版者	NATURE PUBLISHING GROUP
引用统计	被引频次：269[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/133015
专题	中国科学院金属研究所
通讯作者	Wu, Qiang; Wang, Peng; Hu, Zheng
作者单位	1.Nanjing Univ, Key Lab Mesoscop Chem, MOE, Nanjing 210023, Jiangsu, Peoples R China 2.Nanjing Univ, Jiangsu Prov Lab Nanotechnol, Sch Chem & Chem Engn, Nanjing 210023, Jiangsu, Peoples R China 3.Nanjing Univ, Natl Lab Solid State Microstruct, Coll Engn & Appl Sci, Nanjing 210093, Jiangsu, Peoples R China 4.Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China 5.Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China 6.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 7.Nanjing Univ, Res Ctr Environm Nanotechnol ReCENT, Nanjing 210023, Jiangsu, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Zhiqi,Chen, Yugang,Zhou, Liqi,et al. The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring[J]. NATURE COMMUNICATIONS,2019,10:7.
APA	Zhang, Zhiqi.,Chen, Yugang.,Zhou, Liqi.,Chen, Chi.,Han, Zhen.,...&Hu, Zheng.(2019).The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring.NATURE COMMUNICATIONS,10,7.
MLA	Zhang, Zhiqi,et al."The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring".NATURE COMMUNICATIONS 10(2019):7.