Investigation of electrolytes of the vanadium redox flow battery (VII): Prediction of the viscosity of mixed electrolyte solution (VOSO4 + H2SO4 + H2O) based on Eyring's theory

doi:10.1016/j.jct.2019.02.020

IMR OpenIR

	Investigation of electrolytes of the vanadium redox flow battery (VII): Prediction of the viscosity of mixed electrolyte solution (VOSO4 + H2SO4 + H2O) based on Eyring's theory
	Li, Xiangrong 1; Jiang, Chenglin 1; Qin, Ye 1; Liu, Jianguo 1; Yang, Jiazhen 1,2; Xu, Qian 3; Yan, Chuanwei 1
通讯作者	Qin, Ye(yqin@imr.ac.cn) ; Liu, Jianguo(jgliu@imr.ac.cn)
	2019-07-01
发表期刊	JOURNAL OF CHEMICAL THERMODYNAMICS
ISSN	0021-9614
卷号	134 页码:69-75
摘要	Viscosities of ternary mixtures of VOSO4 + H2SO4 with water were measured across the entire range of total ionic strength (I-T = 1 to 11) mol.kg (1) and over a temperature range of (283.15-318.15) K. The viscosity B-coefficients of the binary aqueous were determined from Jones-Dole equation. Using the B-coefficients, the activation parameters for viscous flow of the solutes were further evaluated. On the basis of Eyring's equation, a semi-empirical method to estimate the viscosity for concentrated and mixed electrolyte solutions was put forward. The estimated viscosity values of VOSO4 + H2SO4 + H2O are in quite good agreement with the corresponding experimental results with the average absolute relative deviation of 0.96%. (C) 2019 Published by Elsevier Ltd.
关键词	Vanadium redox flow battery Vanadyl sulfate Viscosity prediction Eyring's theory Mixed electrolyte solution
资助者	National Natural Science Foundation of China ; Science and technology project of SGCC Key techniques research of ion exchange membrance for vanadium redox flow battery
DOI	10.1016/j.jct.2019.02.020
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[21805290] ; National Natural Science Foundation of China[21706266] ; National Natural Science Foundation of China[21676282] ; National Natural Science Foundation of China[21573257] ; Science and technology project of SGCC Key techniques research of ion exchange membrance for vanadium redox flow battery[SGTYHT/16-JS-198]
WOS研究方向	Thermodynamics ; Chemistry
WOS类目	Thermodynamics ; Chemistry, Physical
WOS记录号	WOS:000465000300008
出版者	ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
引用统计	被引频次：12[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/133026
专题	中国科学院金属研究所
通讯作者	Qin, Ye; Liu, Jianguo
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 2.Liaoning Univ, Coll Chem, Shenyang 110036, Liaoning, Peoples R China 3.Shanghai Univ, State Key Lab Adv Special Steel, Shanghai 200072, Peoples R China
推荐引用方式 GB/T 7714	Li, Xiangrong,Jiang, Chenglin,Qin, Ye,et al. Investigation of electrolytes of the vanadium redox flow battery (VII): Prediction of the viscosity of mixed electrolyte solution (VOSO4 + H2SO4 + H2O) based on Eyring's theory[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,2019,134:69-75.
APA	Li, Xiangrong.,Jiang, Chenglin.,Qin, Ye.,Liu, Jianguo.,Yang, Jiazhen.,...&Yan, Chuanwei.(2019).Investigation of electrolytes of the vanadium redox flow battery (VII): Prediction of the viscosity of mixed electrolyte solution (VOSO4 + H2SO4 + H2O) based on Eyring's theory.JOURNAL OF CHEMICAL THERMODYNAMICS,134,69-75.
MLA	Li, Xiangrong,et al."Investigation of electrolytes of the vanadium redox flow battery (VII): Prediction of the viscosity of mixed electrolyte solution (VOSO4 + H2SO4 + H2O) based on Eyring's theory".JOURNAL OF CHEMICAL THERMODYNAMICS 134(2019):69-75.