| Two-dimensional MOF-derived nanoporous Cu/Cu2O networks as catalytic membrane reactor for the continuous reduction of p-nitrophenol | |
| Bai, Xiao-Jue1; Chen, Dan1; Li, Yu-Nong1; Yang, Xi-Man1; Zhang, Ming-Yu1; Wang, Tie-Qiang1; Zhang, Xue-Min1; Zhang, Li-Ying1; Fu, Yu1; Qi, Xuan1; Qi, Wei2 | |
| Corresponding Author | Fu, Yu(fuyu@mail.neu.edu.cn) ; Qi, Xuan(kent.qx@163.com) ; Qi, Wei(wqi@imr.ac.cn) |
| 2019-07-15 | |
| Source Publication | JOURNAL OF MEMBRANE SCIENCE
 |
| ISSN | 0376-7388 |
| Volume | 582Pages:30-36 |
| Abstract | A novel kind of Cu-based catalytic membrane reactor (CMR) has been developed for the efficient reduction of p-nitrophenol (p-NP) to p-aminophenol (p-AP) in a continuous flow-through system. The CMR is prepared by the composite of MOF-derived nanoporous Cu/Cu2O networks and a porous matrix of nylon film. In this process, the pre-synthesized Cu-MOF-nanosheets are deposited onto a porous nylon film via filtration, and then the composite membrane is in-situ reduced by NaBH4 in the liquid phase, producing nanoporous Cu/Cu2O networks/nylon composite membrane. Remarkably, the nanoporous Cu/Cu2O networks exhibit fluffy structure with multidimensional porosity, which shows relatively high mass transportation ability and excellent catalytic activity. Therefore, the nanoporous Cu/Cu2O networks/nylon composite membrane can work as highly efficient and stable CMR, which can continuously convert over 95% of p-NP to p-AP in an 8 h test (8 mL/min) without obvious structure change and deactivation. This new type two-dimensional MOF-derived CMR offers an effective and convenient continuous catalytic process from p-NP to p-AP, which would have a potential application in this industrial reduction reaction. |
| Keyword | Catalytic membrane reactor Two-dimensional MOF Liquid-phase reduction Nanoporous metallic networks Cu/Cu2O |
| Funding Organization | National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Open Project of State Key Laboratory of Supramolecular Structure and Materials |
| DOI | 10.1016/j.memsci.2019.03.055 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[21761132010] ; National Natural Science Foundation of China[91645114] ; National Natural Science Foundation of China[21805028] ; National Natural Science Foundation of China[21805029] ; National Natural Science Foundation of China[21573256] ; Fundamental Research Funds for the Central Universities[N160504002] ; Fundamental Research Funds for the Central Universities[N170503010] ; Fundamental Research Funds for the Central Universities[N180504005] ; Fundamental Research Funds for the Central Universities[N180504007] ; Open Project of State Key Laboratory of Supramolecular Structure and Materials[sklssm201906] ; Open Project of State Key Laboratory of Supramolecular Structure and Materials[sklssm2019027] ; Open Project of State Key Laboratory of Supramolecular Structure and Materials[sklssm2019038] |
| WOS Research Area | Engineering ; Polymer Science |
| WOS Subject | Engineering, Chemical ; Polymer Science |
| WOS ID | WOS:000467250200004 |
| Publisher | ELSEVIER SCIENCE BV |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/133237 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Fu, Yu; Qi, Xuan; Qi, Wei |
| Affiliation | 1.Northeastern Univ, Coll Sci, Dept Chem, Shenyang 110819, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China |
| Recommended Citation GB/T 7714 | Bai, Xiao-Jue,Chen, Dan,Li, Yu-Nong,et al. Two-dimensional MOF-derived nanoporous Cu/Cu2O networks as catalytic membrane reactor for the continuous reduction of p-nitrophenol[J]. JOURNAL OF MEMBRANE SCIENCE,2019,582:30-36. |
| APA | Bai, Xiao-Jue.,Chen, Dan.,Li, Yu-Nong.,Yang, Xi-Man.,Zhang, Ming-Yu.,...&Qi, Wei.(2019).Two-dimensional MOF-derived nanoporous Cu/Cu2O networks as catalytic membrane reactor for the continuous reduction of p-nitrophenol.JOURNAL OF MEMBRANE SCIENCE,582,30-36. |
| MLA | Bai, Xiao-Jue,et al."Two-dimensional MOF-derived nanoporous Cu/Cu2O networks as catalytic membrane reactor for the continuous reduction of p-nitrophenol".JOURNAL OF MEMBRANE SCIENCE 582(2019):30-36. |
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