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Synthesis and electrochemical properties of a new compound, Na0.8Li0.1Ni0.31Mn0.62O2
Liu, Guoqiang1,2,3; Yu, Han1; Liang, Ji5; Zhang, Jingyi1; Wen, Lei4
Corresponding AuthorLiu, Guoqiang(liugq@smm.neu.edu.cn) ; Wen, Lei(leiwen@imr.ac.cn)
2019-07-05
Source PublicationJOURNAL OF ALLOYS AND COMPOUNDS
ISSN0925-8388
Volume792Pages:308-313
AbstractLayered manganese-based oxide is an important cathode material for sodium ion batteries and its performance strongly depends on the composition of the material. Here we synthesize a new compound Na0.8Li0.1Ni0.31Mn0.62O2 by a solid-state reaction method and investigate its electrochemical performance. The resultant material displays a high capacity of 138 mAh g(-1) in the voltage range of 2.0-4.4 V, with good capacity retention. It also displays an excellent rate capability, by delivering a high capacity of 94 mAh g(-1) at a high current density of 788.5 mA g(-1). The sodium ion diffusion coefficient of the Na0.8Li0.1Ni0.31Mn0.62O2 is calculated to be 5.8 x 10 x 12 cm(2) s(-1) by AC impedance testing, which is superior to the previously reported Al-doped P2-Na2/3Ni1/3Mn5/9Al1/9O2 compound. (C) 2019 Published by Elsevier B.V.
KeywordSodium ion batteries Cathode Na0.8Li0.1Ni0.31Mn0.62O2 Electrochemical properties
Funding OrganizationNational Natural Science Foundation of China
DOI10.1016/j.jallcom.2019.04.020
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[51574081]
WOS Research AreaChemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
WOS SubjectChemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS IDWOS:000467235800036
PublisherELSEVIER SCIENCE SA
Citation statistics
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/133266
Collection中国科学院金属研究所
Corresponding AuthorLiu, Guoqiang; Wen, Lei
Affiliation1.Northeastern Univ, Sch Met, Shenyang 110819, Liaoning, Peoples R China
2.Nankai Univ, Coll Chem, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China
3.Northeastern Univ, Sch Met, Liaoning Key Lab Met Sensor Technol, Shenyang 110819, Liaoning, Peoples R China
4.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
5.Univ Wollongong, Australian Inst Innovat Mat, Inst Superconducting & Elect Mat, Innovation Campus,Squires Way, North Wollongong, NSW 2500, Australia
Recommended Citation
GB/T 7714
Liu, Guoqiang,Yu, Han,Liang, Ji,et al. Synthesis and electrochemical properties of a new compound, Na0.8Li0.1Ni0.31Mn0.62O2[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2019,792:308-313.
APA Liu, Guoqiang,Yu, Han,Liang, Ji,Zhang, Jingyi,&Wen, Lei.(2019).Synthesis and electrochemical properties of a new compound, Na0.8Li0.1Ni0.31Mn0.62O2.JOURNAL OF ALLOYS AND COMPOUNDS,792,308-313.
MLA Liu, Guoqiang,et al."Synthesis and electrochemical properties of a new compound, Na0.8Li0.1Ni0.31Mn0.62O2".JOURNAL OF ALLOYS AND COMPOUNDS 792(2019):308-313.
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