Size-Independent Fast Ion Intercalation in Two-Dimensional Titania Nanosheets for Alkali-Metal-Ion Batteries

doi:10.1002/anie.201902478

IMR OpenIR

	Size-Independent Fast Ion Intercalation in Two-Dimensional Titania Nanosheets for Alkali-Metal-Ion Batteries
	Yang, Jinlin 1; Xiao, Xu 2,3; Gong, Wenbin 4; Zhao, Liang 5; Li, Guohui 1; Jiang, Kun 1; Ma, Renzhi 6; Rummeli, Mark H.5; Li, Feng 7; Sasaki, Takayoshi 6; Geng, Fengxia 1
通讯作者	Geng, Fengxia(gengfx@suda.edu.cn)
	2019-06-24
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN	1433-7851
卷号	58 期号:26 页码:8740-8745
摘要	Compared to lithium ions, the fast redox intercalation of large-radius sodium or potassium ions into a solid lattice in non-aqueous electrolytes is an elusive goal. Herein, by regulating the interlayer structure of stacked titania sheets through weakened layer-to-layer interactions and a robustly pillared gallery space, the two-dimensional channel between neighboring sheets was completely open to guest intercalation, allowing fast intercalation that was practically irrespective of the carrier-ion sizes. Regardless of employing regular Li or large-radius Na and K ions, the material manifested zero strain-like behavior with no significant change in both host structure and interlayer space, enabling comparable capacities for all tested ions along with excellent rate behaviors and extraordinarily long lifetimes, even with 80-mu m-thick electrodes. The result highlights the importance of interlayer structural features for unlocking the electrochemical activity of a layered material.
关键词	alkali-ion batteries intercalation lithium pseudocapacitance titania sheets
资助者	National Natural Science Foundation of China ; Thousand Young Talents Program
DOI	10.1002/anie.201902478
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51772201] ; National Natural Science Foundation of China[51402204] ; Thousand Young Talents Program
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000474806700018
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：57[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/134449
专题	中国科学院金属研究所
通讯作者	Geng, Fengxia
作者单位	1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China 2.Drexel Univ, AJ Drexel Nanomat Inst, Philadelphia, PA 19104 USA 3.Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA 4.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Key Lab Nanodevices & Applicat, Suzhou 215123, Peoples R China 5.Soochow Univ, Coll Energy, Soochow Inst Energy & Mat Innovat, Suzhou 215006, Peoples R China 6.Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton, Tsukuba, Ibaraki 3050044, Japan 7.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Yang, Jinlin,Xiao, Xu,Gong, Wenbin,et al. Size-Independent Fast Ion Intercalation in Two-Dimensional Titania Nanosheets for Alkali-Metal-Ion Batteries[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(26):8740-8745.
APA	Yang, Jinlin.,Xiao, Xu.,Gong, Wenbin.,Zhao, Liang.,Li, Guohui.,...&Geng, Fengxia.(2019).Size-Independent Fast Ion Intercalation in Two-Dimensional Titania Nanosheets for Alkali-Metal-Ion Batteries.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(26),8740-8745.
MLA	Yang, Jinlin,et al."Size-Independent Fast Ion Intercalation in Two-Dimensional Titania Nanosheets for Alkali-Metal-Ion Batteries".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.26(2019):8740-8745.