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Water-enhanced selective hydrogenation of cinnamaldehyde to cinnamyl alcohol on RuSnB/CeO2 catalysts
Dai, Yihu1; Chu, Xiaofang1; Gu, Jingjing1; Gao, Xing1; Xu, Min1; Lu, Di1; Wan, Xiaoyue1; Qi, Wei2; Zhang, Bingsen2; Yang, Yanhui1
Corresponding AuthorDai, Yihu(ias_yhdai@njtech.edu.cn) ; Qi, Wei(wqi@imr.ac.cn) ; Yang, Yanhui(yhyang@njtech.edu.cn)
2019-07-25
Source PublicationAPPLIED CATALYSIS A-GENERAL
ISSN0926-860X
Volume582Pages:11
AbstractThe CeO2-supported ternary RuSnB catalysts were synthesized by incipient wetness impregnation procedures and applied in hydrogenation of cinnamaldehyde in pure water as the solvent. A synergy effect between Ru-based catalysts and water molecules has afforded the efficiently selective transformation of cinnamaldehyde to cinnamyl alcohol with the satisfactory conversion and selectivity. Structural characterization results suggested the incorporation of Ru sites into the SnOx matrix and the electronic interaction between Ru and B additives in RuSnB/CeO2 catalyst. The isotopic exchange studies have demonstrated that both dissociative activation of H-2 and H2O (deuterated D-2 and D2O) were apparently affected by the status of Ru sites. Furthermore, the kinetics tests in D2O solvent have also revealed the co-existence of water-involved hydrogen-exchange route with the direct hydrogenation route using dissociative H-2 during the hydrogenation reaction. The optimal Ru2Sn1Bi1/CeO2 catalyst could afford the best H2O-activation capability and thus accelerate the reaction rate in the H2O involved hydrogenation.
KeywordWater Ru catalyst Hydrogen exchange Selective hydrogenation alpha,beta-unsaturated aldehyde and alcohol
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China (Jiangsu Provincial Department of Education) ; National Natural Science Foundation of China (Natural Science Foundation) ; Nanjing Technology Innovation Fund for Overseas Talents
DOI10.1016/j.apcata.2019.05.032
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[21802070] ; National Natural Science Foundation of China[91645114] ; National Natural Science Foundation of China[21573256] ; National Natural Science Foundation of China[21761132010] ; National Natural Science Foundation of China (Jiangsu Provincial Department of Education) ; National Natural Science Foundation of China (Natural Science Foundation)[17KJB150021] ; National Natural Science Foundation of China (Natural Science Foundation)[BK20170986] ; Nanjing Technology Innovation Fund for Overseas Talents
WOS Research AreaChemistry ; Environmental Sciences & Ecology
WOS SubjectChemistry, Physical ; Environmental Sciences
WOS IDWOS:000477790800009
PublisherELSEVIER
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/134713
Collection中国科学院金属研究所
Corresponding AuthorDai, Yihu; Qi, Wei; Yang, Yanhui
Affiliation1.Nanjing Tech Univ, Sch Chem & Mol Engn, Inst Adv Synth, Nanjing 211816, Jiangsu, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Dai, Yihu,Chu, Xiaofang,Gu, Jingjing,et al. Water-enhanced selective hydrogenation of cinnamaldehyde to cinnamyl alcohol on RuSnB/CeO2 catalysts[J]. APPLIED CATALYSIS A-GENERAL,2019,582:11.
APA Dai, Yihu.,Chu, Xiaofang.,Gu, Jingjing.,Gao, Xing.,Xu, Min.,...&Yang, Yanhui.(2019).Water-enhanced selective hydrogenation of cinnamaldehyde to cinnamyl alcohol on RuSnB/CeO2 catalysts.APPLIED CATALYSIS A-GENERAL,582,11.
MLA Dai, Yihu,et al."Water-enhanced selective hydrogenation of cinnamaldehyde to cinnamyl alcohol on RuSnB/CeO2 catalysts".APPLIED CATALYSIS A-GENERAL 582(2019):11.
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