A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System | |
Tong, Qiaolin1; Liu, Yang1; Gao, Xuezhi1; Fan, Zhanfang1; Liu, Tianfu2; Li, Bo2; Su, Dangsheng2,3; Wang, Qinghe1; Cheng, Maosheng1 | |
Corresponding Author | Liu, Yang(y.liu@syphu.edu.cn) ; Wang, Qinghe(qinghe-wang@163.com) ; Cheng, Maosheng(mscheng@syphu.edu.cn) |
2019-07-02 | |
Source Publication | ADVANCED SYNTHESIS & CATALYSIS
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ISSN | 1615-4150 |
Volume | 361Issue:13Pages:3137-3145 |
Abstract | The deoximation of a wide range of ketoximes and aldoximes to their corresponding carbonyl compounds with high yields has been achieved using graphene oxide (GO) and sodium nitrite (NaNO2) as highly efficient catalysts and air as the green oxidant under mild conditions. The mechanism of deprotection and recycling use of catalyst were revealed in deep experiment. The carboxylic acid groups on the GO were essential for high catalytic activity. |
Keyword | Deoximation Graphene oxide Sodium nitrite Air Oximes |
Funding Organization | National Natural Science Foundation of China ; Program for Liaoning Innovative Talents in University ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University |
DOI | 10.1002/adsc.201900202 |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Natural Science Foundation of China[81473087] ; National Natural Science Foundation of China[81872752] ; Program for Liaoning Innovative Talents in University[LR2017043] ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University[ZQN2016005] |
WOS Research Area | Chemistry |
WOS Subject | Chemistry, Applied ; Chemistry, Organic |
WOS ID | WOS:000484142600013 |
Publisher | WILEY-V C H VERLAG GMBH |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/135253 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Liu, Yang; Wang, Qinghe; Cheng, Maosheng |
Affiliation | 1.Shenyang Pharmaceut Univ, Sch Pharmaceut Engn, Minist Educ, Key Lab Struct Based Drug Design & Discovery, Shenyang 110016, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
Recommended Citation GB/T 7714 | Tong, Qiaolin,Liu, Yang,Gao, Xuezhi,et al. A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System[J]. ADVANCED SYNTHESIS & CATALYSIS,2019,361(13):3137-3145. |
APA | Tong, Qiaolin.,Liu, Yang.,Gao, Xuezhi.,Fan, Zhanfang.,Liu, Tianfu.,...&Cheng, Maosheng.(2019).A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System.ADVANCED SYNTHESIS & CATALYSIS,361(13),3137-3145. |
MLA | Tong, Qiaolin,et al."A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System".ADVANCED SYNTHESIS & CATALYSIS 361.13(2019):3137-3145. |
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