A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System

doi:10.1002/adsc.201900202

IMR OpenIR

	A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System
	Tong, Qiaolin 1; Liu, Yang 1; Gao, Xuezhi 1; Fan, Zhanfang 1; Liu, Tianfu 2; Li, Bo 2; Su, Dangsheng 2,3; Wang, Qinghe 1; Cheng, Maosheng 1
Corresponding Author	Liu, Yang(y.liu@syphu.edu.cn) ; Wang, Qinghe(qinghe-wang@163.com) ; Cheng, Maosheng(mscheng@syphu.edu.cn)
	2019-07-02
Source Publication	ADVANCED SYNTHESIS & CATALYSIS
ISSN	1615-4150
Volume	361 Issue:13 Pages:3137-3145
Abstract	The deoximation of a wide range of ketoximes and aldoximes to their corresponding carbonyl compounds with high yields has been achieved using graphene oxide (GO) and sodium nitrite (NaNO2) as highly efficient catalysts and air as the green oxidant under mild conditions. The mechanism of deprotection and recycling use of catalyst were revealed in deep experiment. The carboxylic acid groups on the GO were essential for high catalytic activity.
Keyword	Deoximation Graphene oxide Sodium nitrite Air Oximes
Funding Organization	National Natural Science Foundation of China ; Program for Liaoning Innovative Talents in University ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University
DOI	10.1002/adsc.201900202
Indexed By	SCI
Language	英语
Funding Project	National Natural Science Foundation of China[81473087] ; National Natural Science Foundation of China[81872752] ; Program for Liaoning Innovative Talents in University[LR2017043] ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University[ZQN2016005]
WOS Research Area	Chemistry
WOS Subject	Chemistry, Applied ; Chemistry, Organic
WOS ID	WOS:000484142600013
Publisher	WILEY-V C H VERLAG GMBH
Citation statistics	Cited Times:2[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.imr.ac.cn/handle/321006/135253
Collection	中国科学院金属研究所
Corresponding Author	Liu, Yang; Wang, Qinghe; Cheng, Maosheng
Affiliation	1.Shenyang Pharmaceut Univ, Sch Pharmaceut Engn, Minist Educ, Key Lab Struct Based Drug Design & Discovery, Shenyang 110016, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation GB/T 7714	Tong, Qiaolin,Liu, Yang,Gao, Xuezhi,et al. A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System[J]. ADVANCED SYNTHESIS & CATALYSIS,2019,361(13):3137-3145.
APA	Tong, Qiaolin.,Liu, Yang.,Gao, Xuezhi.,Fan, Zhanfang.,Liu, Tianfu.,...&Cheng, Maosheng.(2019).A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System.ADVANCED SYNTHESIS & CATALYSIS,361(13),3137-3145.
MLA	Tong, Qiaolin,et al."A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System".ADVANCED SYNTHESIS & CATALYSIS 361.13(2019):3137-3145.

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