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A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System
Tong, Qiaolin1; Liu, Yang1; Gao, Xuezhi1; Fan, Zhanfang1; Liu, Tianfu2; Li, Bo2; Su, Dangsheng2,3; Wang, Qinghe1; Cheng, Maosheng1
Corresponding AuthorLiu, Yang(y.liu@syphu.edu.cn) ; Wang, Qinghe(qinghe-wang@163.com) ; Cheng, Maosheng(mscheng@syphu.edu.cn)
2019-07-02
Source PublicationADVANCED SYNTHESIS & CATALYSIS
ISSN1615-4150
Volume361Issue:13Pages:3137-3145
AbstractThe deoximation of a wide range of ketoximes and aldoximes to their corresponding carbonyl compounds with high yields has been achieved using graphene oxide (GO) and sodium nitrite (NaNO2) as highly efficient catalysts and air as the green oxidant under mild conditions. The mechanism of deprotection and recycling use of catalyst were revealed in deep experiment. The carboxylic acid groups on the GO were essential for high catalytic activity.
KeywordDeoximation Graphene oxide Sodium nitrite Air Oximes
Funding OrganizationNational Natural Science Foundation of China ; Program for Liaoning Innovative Talents in University ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University
DOI10.1002/adsc.201900202
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[81473087] ; National Natural Science Foundation of China[81872752] ; Program for Liaoning Innovative Talents in University[LR2017043] ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University[ZQN2016005]
WOS Research AreaChemistry
WOS SubjectChemistry, Applied ; Chemistry, Organic
WOS IDWOS:000484142600013
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/135256
Collection中国科学院金属研究所
Corresponding AuthorLiu, Yang; Wang, Qinghe; Cheng, Maosheng
Affiliation1.Shenyang Pharmaceut Univ, Sch Pharmaceut Engn, Minist Educ, Key Lab Struct Based Drug Design & Discovery, Shenyang 110016, Liaoning, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Tong, Qiaolin,Liu, Yang,Gao, Xuezhi,et al. A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System[J]. ADVANCED SYNTHESIS & CATALYSIS,2019,361(13):3137-3145.
APA Tong, Qiaolin.,Liu, Yang.,Gao, Xuezhi.,Fan, Zhanfang.,Liu, Tianfu.,...&Cheng, Maosheng.(2019).A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System.ADVANCED SYNTHESIS & CATALYSIS,361(13),3137-3145.
MLA Tong, Qiaolin,et al."A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System".ADVANCED SYNTHESIS & CATALYSIS 361.13(2019):3137-3145.
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