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Increasing Solar Absorption of Atomically Thin 2D Carbon Nitride Sheets for Enhanced Visible-Light Photocatalysis
Wang, Yong1,2; Du, Peipei3; Pan, Hongzhe4; Fu, Lin1,2; Zhang, Yu1,2; Chen, Jie1,2; Du, Youwei1,2; Tang, Nujiang1,2; Liu, Gang3,5
Corresponding AuthorTang, Nujiang(tangnujiang@nju.edu.cn) ; Liu, Gang(gangliu@imr.ac.cn)
2019-08-22
Source PublicationADVANCED MATERIALS
ISSN0935-9648
Pages8
AbstractAtomically thin 2D carbon nitride sheets (CNS) are promising materials for photocatalytic applications due to their large surface area and very short charge-carrier diffusion distance from the bulk to the surface. However, compared to their bulk counterpart, CNS' applications always suffer from an enlarged bandgap and thus narrowed solar absorption range. Here, an approach to significantly increase solar absorption of the atomically thin CNS via fluorination followed by thermal defluorination is reported. This approach can greatly increase the visible-light absorption of CNS by extending the absorption edge up to 578 nm. The modulated CNS loaded with Pt cocatalyst as a photocatalyst shows a superior photocatalytic hydrogen production activity under visible-light irradiation to Pt-CNS. Combining experimental characterization with theoretical calculations shows that this approach can introduce cyano groups into the framework of CNS as well as the accompanied nitrogen vacancies at the edges, which leads to both narrowing the bandgap and changing the charge distribution. This study will provide an effective strategy to increase solar absorption of carbon-nitride-based photocatalysts for solar energy conversion applications.
Keyword2D materials carbon nitride fluorination and defluorination photocatalysts visible light
Funding OrganizationState Key Program for Basic Research ; National Natural Science Foundation of China
DOI10.1002/adma.201807540
Indexed BySCI
Language英语
Funding ProjectState Key Program for Basic Research[2017YFA0206304] ; National Natural Science Foundation of China[51572122] ; National Natural Science Foundation of China[51825204] ; National Natural Science Foundation of China[51572266]
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:000483162200001
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:46[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/135323
Collection中国科学院金属研究所
Corresponding AuthorTang, Nujiang; Liu, Gang
Affiliation1.Nanjing Univ, Natl Lab Solid State Microstruct, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China
2.Nanjing Univ, Jiangsu Prov Key Lab Nanotechnol, Nanjing 210093, Jiangsu, Peoples R China
3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
4.Linyi Univ, Sch Phys & Elect Engn, Linyi 276005, Shandong, Peoples R China
5.Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Wang, Yong,Du, Peipei,Pan, Hongzhe,et al. Increasing Solar Absorption of Atomically Thin 2D Carbon Nitride Sheets for Enhanced Visible-Light Photocatalysis[J]. ADVANCED MATERIALS,2019:8.
APA Wang, Yong.,Du, Peipei.,Pan, Hongzhe.,Fu, Lin.,Zhang, Yu.,...&Liu, Gang.(2019).Increasing Solar Absorption of Atomically Thin 2D Carbon Nitride Sheets for Enhanced Visible-Light Photocatalysis.ADVANCED MATERIALS,8.
MLA Wang, Yong,et al."Increasing Solar Absorption of Atomically Thin 2D Carbon Nitride Sheets for Enhanced Visible-Light Photocatalysis".ADVANCED MATERIALS (2019):8.
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