Three-Dimensional Interconnected Porous Nitrogen-Doped Carbon Hybrid Foam for Notably Promoted Direct Dehydrogenation of Ethylbenzene to Styrene

doi:10.1002/cctc.201901291

IMR OpenIR

	Three-Dimensional Interconnected Porous Nitrogen-Doped Carbon Hybrid Foam for Notably Promoted Direct Dehydrogenation of Ethylbenzene to Styrene
	Ge, Guifang 1; Liu, Hongyang 2; Zhao, Zhongkui 1
通讯作者	Liu, Hongyang(liuhy@imr.ac.cn) ; Zhao, Zhongkui(zkzhao@dlut.edu.cn)
	2019-09-16
发表期刊	CHEMCATCHEM
ISSN	1867-3880
页码	12
摘要	Owning to the high corrosion-resistance, stable structure, unique surface properties and sustainability, the carbon-base catalysts have attracted increasing interest in heterogeneous catalysis. Herein, we report a facile combining strategy to fabricate a novel three-dimensional (3D) interconnected porous nitrogen-doped carbon hybrid foam featuring with the interconnected nitrogen-doped carbon foam coated by porous nitrogen-doped carbon (NCMS@NCGlu-NH4Cl) by annealing the freeze-dried NH4Cl-glucose containing aqueous solution soaked melamine sponge (MS@Glu/NH4Cl). The as-prepared NCMS@NCGlu-NH4Cl hybrid foam shows 1.6 times high steady-state styrene rate (4.77 mmol g(-1) h(-1)) with 96.4 % of selectivity for direct dehydrogenation of ethylbenzene to styrene as compared to the well-established nanodiamond. This work not only generates an excellent carbon catalyst to replace the established nanodiamond for direct dehydrogenation of ethylbenzene, but also opens up a potential avenue for designing novel carbon materials towards the adsorption and supercapacitor besides acting as a promising catalyst for diverse transformations.
关键词	combining strategy ammonium chloride and freeze drying porous nitrogen-doped carbon hybrid foam 3D interconnected structure dehydrogenation of ethylbenzene
资助者	National Natural Science Foundation of China ; Chinese Ministry of Education via the Program for New Century Excellent Talents in Universities
DOI	10.1002/cctc.201901291
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[21676046] ; Chinese Ministry of Education via the Program for New Century Excellent Talents in Universities[NCET-12-0079]
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:000486762900001
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/135555
专题	中国科学院金属研究所
通讯作者	Liu, Hongyang; Zhao, Zhongkui
作者单位	1.Dalian Univ Technol, Sch Chem Engn, Dept Catalysis Chem & Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Ge, Guifang,Liu, Hongyang,Zhao, Zhongkui. Three-Dimensional Interconnected Porous Nitrogen-Doped Carbon Hybrid Foam for Notably Promoted Direct Dehydrogenation of Ethylbenzene to Styrene[J]. CHEMCATCHEM,2019:12.
APA	Ge, Guifang,Liu, Hongyang,&Zhao, Zhongkui.(2019).Three-Dimensional Interconnected Porous Nitrogen-Doped Carbon Hybrid Foam for Notably Promoted Direct Dehydrogenation of Ethylbenzene to Styrene.CHEMCATCHEM,12.
MLA	Ge, Guifang,et al."Three-Dimensional Interconnected Porous Nitrogen-Doped Carbon Hybrid Foam for Notably Promoted Direct Dehydrogenation of Ethylbenzene to Styrene".CHEMCATCHEM (2019):12.