| Three-Dimensional Interconnected Porous Nitrogen-Doped Carbon Hybrid Foam for Notably Promoted Direct Dehydrogenation of Ethylbenzene to Styrene | |
| Ge, Guifang1; Liu, Hongyang2; Zhao, Zhongkui1 | |
| Corresponding Author | Liu, Hongyang(liuhy@imr.ac.cn) ; Zhao, Zhongkui(zkzhao@dlut.edu.cn) |
| 2019-09-16 | |
| Source Publication | CHEMCATCHEM
 |
| ISSN | 1867-3880 |
| Pages | 12 |
| Abstract | Owning to the high corrosion-resistance, stable structure, unique surface properties and sustainability, the carbon-base catalysts have attracted increasing interest in heterogeneous catalysis. Herein, we report a facile combining strategy to fabricate a novel three-dimensional (3D) interconnected porous nitrogen-doped carbon hybrid foam featuring with the interconnected nitrogen-doped carbon foam coated by porous nitrogen-doped carbon (NCMS@NCGlu-NH4Cl) by annealing the freeze-dried NH4Cl-glucose containing aqueous solution soaked melamine sponge (MS@Glu/NH4Cl). The as-prepared NCMS@NCGlu-NH4Cl hybrid foam shows 1.6 times high steady-state styrene rate (4.77 mmol g(-1) h(-1)) with 96.4 % of selectivity for direct dehydrogenation of ethylbenzene to styrene as compared to the well-established nanodiamond. This work not only generates an excellent carbon catalyst to replace the established nanodiamond for direct dehydrogenation of ethylbenzene, but also opens up a potential avenue for designing novel carbon materials towards the adsorption and supercapacitor besides acting as a promising catalyst for diverse transformations. |
| Keyword | combining strategy ammonium chloride and freeze drying porous nitrogen-doped carbon hybrid foam 3D interconnected structure dehydrogenation of ethylbenzene |
| Funding Organization | National Natural Science Foundation of China ; Chinese Ministry of Education via the Program for New Century Excellent Talents in Universities |
| DOI | 10.1002/cctc.201901291 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[21676046] ; Chinese Ministry of Education via the Program for New Century Excellent Talents in Universities[NCET-12-0079] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Physical |
| WOS ID | WOS:000486762900001 |
| Publisher | WILEY-V C H VERLAG GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/135555 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Liu, Hongyang; Zhao, Zhongkui |
| Affiliation | 1.Dalian Univ Technol, Sch Chem Engn, Dept Catalysis Chem & Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China |
| Recommended Citation GB/T 7714 | Ge, Guifang,Liu, Hongyang,Zhao, Zhongkui. Three-Dimensional Interconnected Porous Nitrogen-Doped Carbon Hybrid Foam for Notably Promoted Direct Dehydrogenation of Ethylbenzene to Styrene[J]. CHEMCATCHEM,2019:12. |
| APA | Ge, Guifang,Liu, Hongyang,&Zhao, Zhongkui.(2019).Three-Dimensional Interconnected Porous Nitrogen-Doped Carbon Hybrid Foam for Notably Promoted Direct Dehydrogenation of Ethylbenzene to Styrene.CHEMCATCHEM,12. |
| MLA | Ge, Guifang,et al."Three-Dimensional Interconnected Porous Nitrogen-Doped Carbon Hybrid Foam for Notably Promoted Direct Dehydrogenation of Ethylbenzene to Styrene".CHEMCATCHEM (2019):12. |
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