Anchoring Cu-1 species over nanodiamond-graphene for semi-hydrogenation of acetylene

doi:10.1038/s41467-019-12460-7

IMR OpenIR

	Anchoring Cu-1 species over nanodiamond-graphene for semi-hydrogenation of acetylene
	Huang, Fei 1,2; Deng, Yuchen 3,4; Chen, Yunlei 5,6; Cai, Xiangbin 7; Peng, Mi 3,4; Jia, Zhimin 1,2; Xie, Jinglin 3,4; Xiao, Dequan 8; Wen, Xiaodong 5,9; Wang, Ning 7; Jiang, Zheng 10,11; Liu, Hongyang 1,2; Ma, Ding 3,4
通讯作者	Jiang, Zheng(jiangzheng@sinap.ac.cn) ; Liu, Hongyang(liuhy@imr.ac.cn) ; Ma, Ding(dma@pku.edu.cn)
	2019-09-30
发表期刊	NATURE COMMUNICATIONS
ISSN	2041-1723
卷号	10 页码:7
摘要	The design of cheap, non-toxic, and earth-abundant transition metal catalysts for selective hydrogenation of alkynes remains a challenge in both industry and academia. Here, we report a new atomically dispersed copper (Cu) catalyst supported on a defective nanodiamond-graphene (ND@G), which exhibits excellent catalytic performance for the selective conversion of acetylene to ethylene, i.e., with high conversion (95%), high selectivity (98%), and good stability (for more than 60 h). The unique structural feature of the Cu atoms anchored over graphene through Cu-C bonds ensures the effective activation of acetylene and easy desorption of ethylene, which is the key for the outstanding activity and selectivity of the catalyst.
资助者	Ministry of Science and Technology ; National Natural Science Foundation of China ; Joint Fund of National Natural Science Foundation of China ; Youth Innovation Promotion Association ; Chinese Academy of Science (CAS) ; Research Grants Council of Hong Kong
DOI	10.1038/s41467-019-12460-7
收录类别	SCI
语种	英语
资助项目	Ministry of Science and Technology[2016YFA0204100] ; Ministry of Science and Technology[2017YFB0602200] ; National Natural Science Foundation of China[91845201] ; National Natural Science Foundation of China[21573254] ; National Natural Science Foundation of China[91545110] ; National Natural Science Foundation of China[21725301] ; National Natural Science Foundation of China[91645115] ; National Natural Science Foundation of China[21932002] ; National Natural Science Foundation of China[21473003] ; Joint Fund of National Natural Science Foundation of China[U1732667] ; Youth Innovation Promotion Association ; Chinese Academy of Science (CAS) ; Research Grants Council of Hong Kong[16306818] ; Research Grants Council of Hong Kong[C6021-14E]
WOS研究方向	Science & Technology - Other Topics
WOS类目	Multidisciplinary Sciences
WOS记录号	WOS:000488235000001
出版者	NATURE PUBLISHING GROUP
引用统计	被引频次：266[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/135814
专题	中国科学院金属研究所
通讯作者	Jiang, Zheng; Liu, Hongyang; Ma, Ding
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China 3.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Engn, Beijing 100871, Peoples R China 4.Peking Univ, Coll Engn, BIC ESAT, Beijing 100871, Peoples R China 5.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China 6.Univ Chinese Acad Sci, 19A Yuanquan Rd, Beijing 100049, Peoples R China 7.Hong Kong Univ Sci & Technol, Dept Phys, Kowloon, Clear Water Bay, Hong Kong, Peoples R China 8.Univ New Haven, Ctr Integrat Mat Discovery, Dept Chem & Chem Engn, 300 Boston Post Rd, West Haven, CT 06516 USA 9.Synfuels China Co Ltd, Natl Energy Ctr Coal Clean Fuel, Beijing 101400, Peoples R China 10.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China 11.Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai Synchrotron Radiat Facil, Shanghai 201210, Peoples R China
推荐引用方式 GB/T 7714	Huang, Fei,Deng, Yuchen,Chen, Yunlei,et al. Anchoring Cu-1 species over nanodiamond-graphene for semi-hydrogenation of acetylene[J]. NATURE COMMUNICATIONS,2019,10:7.
APA	Huang, Fei.,Deng, Yuchen.,Chen, Yunlei.,Cai, Xiangbin.,Peng, Mi.,...&Ma, Ding.(2019).Anchoring Cu-1 species over nanodiamond-graphene for semi-hydrogenation of acetylene.NATURE COMMUNICATIONS,10,7.
MLA	Huang, Fei,et al."Anchoring Cu-1 species over nanodiamond-graphene for semi-hydrogenation of acetylene".NATURE COMMUNICATIONS 10(2019):7.