MoOx Nanoparticle Catalysts for D-Glucose Epimerization and Their Electrical Immobilization in a Continuous Flow Reactor

doi:10.1021/acsami.9b13848

IMR OpenIR

	MoOx Nanoparticle Catalysts for D-Glucose Epimerization and Their Electrical Immobilization in a Continuous Flow Reactor
	Zhang, Yexin 1,5; Chen, Hui 1,5; Gao, Yijing 2; Yao, Zihao 2; Wang, Jianguo 2; Zhang, Bingsen 3,5; Luo, Kan 1; Du, Shiyu 1,5; Su, Dang Sheng 4,5; Zhang, Jian 1,5
通讯作者	Wang, Jianguo(jgw@zjut.edu.cn) ; Zhang, Jian(jzhang@nimte.ac.cn)
	2019-11-27
发表期刊	ACS APPLIED MATERIALS & INTERFACES
ISSN	1944-8244
卷号	11 期号:47 页码:44118-44123
摘要	Activity and immobilization of catalysts in liquid-phase reactions seem not to coexist. We report here the excellent activity of an MoOx nanoparticle (NP) catalyst for D-glucose epimerization to D-mannose and the electrical immobilization of NPs in a flow reaction. Prior to that, a green and one-pot method to synthesize the MoOx NPs (3.05 nm) via oxidizing metal Mo by hydrogen peroxide was presented. The NPs overwhelmed the reported catalysts including epimerase for D-glucose epimerization, originating from a strong interaction between the NPs and the reactant that was demonstrated by ex situ and in situ characterizations and theoretical calculations. The electrically charged feature of NPs inspired us to find a convenient way to "immobilize" them inside an activated carbon bed, and thereby, a flow reactor was assembled. The continuous epimerization was run under 24 V for 16 days with an almost unchanged activity, and only 3.2% of total Mo was lost.
关键词	molybdenum oxides nanoparticles D-glucose epimerization electrical immobilization
资助者	National Natural Science Foundation of China ; Key Research Program of Chinese Academy of Sciences ; Key Research Program of Frontier Sciences, Chinese Academy of Sciences ; Fujian Institute of Innovation, Chinese Academy of Sciences ; Zhejiang Provincial Natural Science Foundation of China ; K.C. Wong Education Foundation ; Ningbo Science and Technology Bureau
DOI	10.1021/acsami.9b13848
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51422212] ; National Natural Science Foundation of China[21403261] ; National Natural Science Foundation of China[21625604] ; Key Research Program of Chinese Academy of Sciences[ZDRW-CN-2016-1] ; Key Research Program of Frontier Sciences, Chinese Academy of Sciences[QYZDB-SSW-JS C037] ; Fujian Institute of Innovation, Chinese Academy of Sciences[FJCXY18020202] ; Zhejiang Provincial Natural Science Foundation of China[LY19B030003] ; Zhejiang Provincial Natural Science Foundation of China[LQ19B060002] ; Zhejiang Provincial Natural Science Foundation of China[R16B030001] ; K.C. Wong Education Foundation[rczx0800] ; Ningbo Science and Technology Bureau[2018B10056] ; Ningbo Science and Technology Bureau[2017C110028]
WOS研究方向	Science & Technology - Other Topics ; Materials Science
WOS类目	Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000500415700030
出版者	AMER CHEMICAL SOC
引用统计	被引频次：8[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/135984
专题	中国科学院金属研究所
通讯作者	Wang, Jianguo; Zhang, Jian
作者单位	1.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Biobased Polymer Mat Technol & Applicat Z, 1219 Zhongguan West Rd, Ningbo 315201, Zhejiang, Peoples R China 2.Zhejiang Univ Technol, Coll Chem Engn, State Key Lab Breeding Base Green Chem Synth Tech, Inst Ind Catalysis, 18 Chaowang Rd, Hangzhou 310032, Zhejiang, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 5.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Yexin,Chen, Hui,Gao, Yijing,et al. MoOx Nanoparticle Catalysts for D-Glucose Epimerization and Their Electrical Immobilization in a Continuous Flow Reactor[J]. ACS APPLIED MATERIALS & INTERFACES,2019,11(47):44118-44123.
APA	Zhang, Yexin.,Chen, Hui.,Gao, Yijing.,Yao, Zihao.,Wang, Jianguo.,...&Zhang, Jian.(2019).MoOx Nanoparticle Catalysts for D-Glucose Epimerization and Their Electrical Immobilization in a Continuous Flow Reactor.ACS APPLIED MATERIALS & INTERFACES,11(47),44118-44123.
MLA	Zhang, Yexin,et al."MoOx Nanoparticle Catalysts for D-Glucose Epimerization and Their Electrical Immobilization in a Continuous Flow Reactor".ACS APPLIED MATERIALS & INTERFACES 11.47(2019):44118-44123.