Nonthermal plasma (NTP) activated metal-organic frameworks (MOFs) catalyst for catalytic CO2 hydrogenation

doi:10.1002/aic.16853

IMR OpenIR

	Nonthermal plasma (NTP) activated metal-organic frameworks (MOFs) catalyst for catalytic CO2 hydrogenation
	Chen, Huanhao 1; Mu, Yibing 1; Shao, Yan 1,2; Chansai, Sarayute 1; Xiang, Huan 1; Jiao, Yilai 3; Hardacre, Christopher 1; Fan, Xiaolei 1
通讯作者	Chen, Huanhao(huanhao.chen@manchester.ac.uk)
	2019-11-26
发表期刊	AICHE JOURNAL
ISSN	0001-1541
卷号	66 期号:4 页码:11
摘要	A systematic study of Ni supported on metal-organic frameworks (MOFs) catalyst (i.e., 15Ni/UiO-66) for catalytic CO2 hydrogenation under nonthermal plasma (NTP) conditions was presented. The catalyst outperformed other catalysts based on conventional supports such as ZrO2, representing highest CO2 conversion and CH4 selectivity at about 85 and 99%, respectively. We found that the turnover frequency of the NTP catalysis system (1.8 +/- 0.02 s(-1)) has a nearly two-fold improvement compared with the thermal catalysis (1.0 +/- 0.06 s(-1)). After 20 hr test, XPS and HRTEM characterizations confirmed the stability of the 15Ni/UiO-66 catalyst in the NTP-activated catalysis. The activation barrier for the NTP-activated catalysis was calculated as similar to 32 kJ mol(-1), being lower than the activation energy of the thermal catalysis (similar to 70 kJ mol(-1)). In situ DRIFTS characterization confirmed the formation of multiple carbonates and formates on catalyst surface activated by NTP, surpassing the control catalysts (e.g., 15Ni/alpha-Al2O3 and 15Ni/ZrO2).
资助者	Chinese Scholarship Council (CSC) ; European Commission Marie Sklodowska-Curie Individual Fellowship ; Foundation of Department of Education of Guangdong Province
DOI	10.1002/aic.16853
收录类别	SCI
语种	英语
资助项目	Chinese Scholarship Council (CSC)[201708440477] ; European Commission Marie Sklodowska-Curie Individual Fellowship[H2020-MSCA-IF-NTPleasure-748196] ; Foundation of Department of Education of Guangdong Province[2017KZDXM085] ; Foundation of Department of Education of Guangdong Province[2018KZDXM070]
WOS研究方向	Engineering
WOS类目	Engineering, Chemical
WOS记录号	WOS:000498437100001
出版者	WILEY
引用统计	被引频次：51[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/136041
专题	中国科学院金属研究所
通讯作者	Chen, Huanhao
作者单位	1.Univ Manchester, Sch Engn, Dept Chem Engn & Analyt Sci, Manchester M13 9PL, Lancs, England 2.Wuyi Univ, Sch Biotechnol & Hlth Sci, Jiangmen, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Chen, Huanhao,Mu, Yibing,Shao, Yan,et al. Nonthermal plasma (NTP) activated metal-organic frameworks (MOFs) catalyst for catalytic CO2 hydrogenation[J]. AICHE JOURNAL,2019,66(4):11.
APA	Chen, Huanhao.,Mu, Yibing.,Shao, Yan.,Chansai, Sarayute.,Xiang, Huan.,...&Fan, Xiaolei.(2019).Nonthermal plasma (NTP) activated metal-organic frameworks (MOFs) catalyst for catalytic CO2 hydrogenation.AICHE JOURNAL,66(4),11.
MLA	Chen, Huanhao,et al."Nonthermal plasma (NTP) activated metal-organic frameworks (MOFs) catalyst for catalytic CO2 hydrogenation".AICHE JOURNAL 66.4(2019):11.